819-19-2

  • Product Name:Di-tert-butylphosphine
  • Molecular Formula:C8H19P
  • Purity:99%
  • Molecular Weight:146.213
InquiryAdd to cart

Product Details;

CasNo: 819-19-2

Molecular Formula: C8H19P

Appearance: colourless liquid

factory and supplier 819-19-2 Di-tert-butylphosphine in stock

  • Molecular Formula:C8H19P
  • Molecular Weight:146.213
  • Appearance/Colour:colourless liquid 
  • Vapor Pressure:2.5mmHg at 25°C 
  • Melting Point:-17°C 
  • Boiling Point:165.1 °C at 760 mmHg 
  • Flash Point:-1 °F 
  • Density:0.79 g/mL at 25oC(lit.) 

DI-T-BUTYLPHOSPHINE(Cas 819-19-2) Usage

InChI:InChI=1/C8H19P/c1-7(2,3)9-8(4,5)6/h9H,1-6H3

819-19-2 Relevant articles

On the compatibility of Ruthenium metathesis catalysts with secondary phosphines

Van Lierop, Bianca J.,Fogg, Deryn E.

, p. 7245 - 7248 (2013)

While attempts to incorporate secondary ...

Reactivity of Phosphanylphosphinidene Complex of Tungsten(VI) toward Phosphines: A New Method of Synthesis of catena-Polyphosphorus Ligands

Grubba, Rafa?,Ordyszewska, Anna,Kaniewska, Kinga,Ponikiewski, ?ukasz,Chojnacki, Jaros?aw,Gudat, Dietrich,Pikies, Jerzy

, p. 8380 - 8387 (2015/09/21)

The reactivity of an anionic phosphanylp...

Reactivity of diimido complexes of moybdenum and tungsten towards lithium derivatives of diphosphanes and triphosphanes

Grubba, Rafa?,Wi?niewska, Aleksandra,Ponikiewski, ?ukasz,Caporali, Maria,Peruzzini, Maurizio,Pikies, Jerzy

, p. 1811 - 1817 (2014/04/17)

The reaction of R2P-P(SiMe3)Li (R = tBu,...

Reactivity of diimido complexes of moybdenum and tungsten towards lithium derivatives of diphosphanes and triphosphanes

Grubba, Rafa?,Wis?niewska, Aleksandra,Ponikiewski, ?ukasz,Caporali, Maria,Peruzzini, Maurizio,Pikies, Jerzy

, p. 1811 - 1817 (2015/04/27)

The reaction of R2P-P(SiMe3)Li (R = tBu,...

819-19-2 Process route

[Li<sup>+</sup>*3DME][Cl((2,6-iPr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)N)<sub>2</sub>W(η<sup>2</sup>-t-Bu<sub>2</sub>PP)<sup>-</sup>]

[Li+*3DME][Cl((2,6-iPr2C6H3)N)2W(η2-t-Bu2PP)-]

chloro-diphenylphosphine
1079-66-9,74391-44-9

chloro-diphenylphosphine

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

di-tert-butylphosphine
819-19-2

di-tert-butylphosphine

(1,2-η-t-Bu<sub>2</sub>PPP-t-Bu<sub>2</sub>)W(2,6-i-Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>N)<sub>2</sub>Cl

(1,2-η-t-Bu2PPP-t-Bu2)W(2,6-i-Pr2C6H3N)2Cl

1.1-Diisobutyl-2.2-diphenyldiphosphin
67857-60-7

1.1-Diisobutyl-2.2-diphenyldiphosphin

Tetraphenyldiphosphin
1101-41-3

Tetraphenyldiphosphin

Conditions
Conditions Yield
In 1,2-dimethoxyethane; at -40 - 20 ℃; for 24h; Schlenk technique;
41 %Spectr.
17 %Spectr.
9 %Spectr.
8 %Spectr.
[Li<sup>+</sup>*3DME][Cl((2,6-iPr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)N)<sub>2</sub>W(η<sup>2</sup>-t-Bu<sub>2</sub>PP)<sup>-</sup>]

[Li+*3DME][Cl((2,6-iPr2C6H3)N)2W(η2-t-Bu2PP)-]

Bromodiphenylphosphin
1079-65-8

Bromodiphenylphosphin

di-tert-butylphosphine
819-19-2

di-tert-butylphosphine

(1,2-η-t-Bu<sub>2</sub>PPP-t-Bu<sub>2</sub>)W(2,6-i-Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>N)<sub>2</sub>Cl

(1,2-η-t-Bu2PPP-t-Bu2)W(2,6-i-Pr2C6H3N)2Cl

(1,2-η-t-Bu<sub>2</sub>PPP-t-Bu<sub>2</sub>)W(2,6-i-Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>N)<sub>2</sub>Br

(1,2-η-t-Bu2PPP-t-Bu2)W(2,6-i-Pr2C6H3N)2Br

Tetraphenyldiphosphin
1101-41-3

Tetraphenyldiphosphin

Conditions
Conditions Yield
In toluene; at -40 - 20 ℃; for 24h; Schlenk technique;
54%
19 %Spectr.
19 %Spectr.
14 %Spectr.

819-19-2 Upstream products

  • 67-56-1
    67-56-1

    methanol

  • 119522-06-4
    119522-06-4

    Di-tert-butylphosphine

  • 141-97-9
    141-97-9

    ethyl acetoacetate

  • 62-53-3
    62-53-3

    aniline

819-19-2 Downstream products

  • 26058-95-7
    26058-95-7

    Acetyl-di-tert.-butyl-phosphin

  • 50838-15-8
    50838-15-8

    1-Di-tert-butylphosphino-1-acetoxyethylen

  • 65420-68-0
    65420-68-0

    1,5-bis(di-tert-butylphosphino)pentane

  • 67857-60-7
    67857-60-7

    1.1-Diisobutyl-2.2-diphenyldiphosphin

Relevant Products

Shopping Cart

Clear Inquiry