434-90-2
- Product Name：Decafluorbiphenyl
- Molecular Formula：C12F10
- Purity：99%
- Molecular Weight：334.116
Product Details;
CasNo： 434-90-2
Molecular Formula： C12F10
Appearance： white crystals or powder
factory and supplier 434-90-2 Decafluorbiphenyl in stock
- Molecular Formula:C12F10
- Molecular Weight:334.116
- Appearance/Colour:white crystals or powder
- Vapor Pressure:0.000384mmHg at 25°C
- Melting Point:68-70 °C(lit.)
- Refractive Index:1.642
- Boiling Point:206.1 °C at 760 mmHg
- Flash Point:68.5 °C
- PSA：0.00000
- Density:1.697 g/cm3
- LogP:4.74460
Decafluorobiphenyl(Cas 434-90-2) Usage
InChI:InChI=1/C8H5FN2O/c9-5-2-1-3-6-7(5)8(12)11-4-10-6/h1-4H,(H,10,11,12)
434-90-2 Relevant articles
Ullmann reaction optimization within bitolyl and decafluorobiphenyl synthesis
Kolotaev,Razinov,Khachatryan
, p. 993 - 999 (2018)
This article describes the investigation...
Intriguing Behavior of an Apparently Simple Coupling Promoter Ligand, PPh2(p-C6H4-C6F5), in Their Pd Complexes
Pérez-Iglesias, María,Infante, Rebeca,Casares, Juan A.,Espinet, Pablo
, p. 3688 - 3695 (2019)
Ligand PPh2(p-C6H4-C6F5), LHF, is an exa...
Selective reductive defluorination of dicyclohexyl compounds: Intramolecular coupling reaction by reductive cleavage of C-F bonds
Sung, Kuangsen,Lagow, Richard J.
, p. 637 - 638 (1998)
Reductive defluorination of perfluoro(di...
Pentafluorophenyl transfer: A new group-transfer reaction in organoborate salts
Hewavitharanage, Priyadarshine,Danilov, Evgeny O.,Neckers, Douglas C.
, p. 10653 - 10659 (2005)
Irradiation of isoquinolinium hydroxytri...
Selective synthesis of fluorinated biaryls by [MCl2(PhPEWO-F)] (M = Ni, Pd) catalysed Negishi cross-coupling
Espinet, Pablo,Ponce-De-León, Jaime
supporting information, p. 10875 - 10878 (2021/10/22)
Highly selective cross-couplings to poly...
Convenient Synthesis of Symmetrical Polyfluorinated Diphenyl Sulfides
Bredikhin, R. A.,Maksimov, A. M.,Nikul’shin, P. V.,Platonov, V. E.
, p. 1921 - 1930 (2022/01/24)
Abstract: Thermal properties of decafluo...
Ranking Ligands by Their Ability to Ease (C6F5)2NiIIL → Ni0L + (C6F5)2Coupling versus Hydrolysis: Outstanding Activity of PEWO Ligands
Ponce-De-León, Jaime,Gioria, Estefania,Martínez-Ilarduya, Jesús M.,Espinet, Pablo
supporting information, p. 18287 - 18294 (2020/12/23)
The NiII literature complex cis-[Ni(C6F5...
Palladium-Catalyzed Homocoupling of Highly Fluorinated Arylboronates: Studies of the Influence of Strongly vs Weakly Coordinating Solvents on the Reductive Elimination Process
Budiman, Yudha P.,Friedrich, Alexandra,Jayaraman, Arumugam,Kerner, Florian,Marder, Todd B.,Radius, Udo
supporting information, p. 6036 - 6050 (2020/04/27)
C-C reductive elimination from [PdL2(C6F...
434-90-2 Process route
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552-16-9,104810-18-6
ortho-nitrobenzoic acid
-
-
602-94-8
Pentafluorobenzoic acid
-
-
2436-96-6
1-nitro-2-(2-nitrophenyl)benzene
-
-
434-90-2
decafluorobiphenyl
-
-
25506-47-2
pentafluorophenyl-2′-nitro-1,1′-biphenyl
| Conditions | Yield |
|---|---|
|
With
triphenylphosphine; silver carbonate; palladium dichloride;
In
dimethyl sulfoxide;
at 130 ℃;
for 6h;
Inert atmosphere;
|
54% 32% 11 %Chromat. |
-
-
106-38-7
para-bromotoluene
-
-
potassium perfluorophenyltrifluoroborate
-
-
363-72-4
Pentafluorobenzene
-
-
434-90-2
decafluorobiphenyl
-
-
14621-04-6
2,3,4,5,6-pentafluoro-4'-methylbiphenyl
| Conditions | Yield |
|---|---|
|
With
palladium diacetate; potassium carbonate; silver sulfate; silver(l) oxide;
In
toluene;
at 100 ℃;
for 1h;
Reagent/catalyst;
Inert atmosphere;
Sealed tube;
|
28% 26% 20% |
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