95-69-2
- Product Name:4-Chloro-2-methylaniline
- Molecular Formula:C7H8ClN
- Purity:99%
- Molecular Weight:141.6
Product Details;
CasNo: 95-69-2
Molecular Formula: C7H8ClN
Appearance: clear brown liquid
factory and supplier 95-69-2 4-Chloro-2-methylaniline in stock
- Molecular Formula:C7H8ClN
- Molecular Weight:141.6
- Appearance/Colour:clear brown liquid
- Melting Point:29 °C
- Refractive Index:n20/D 1.583(lit.)
- Boiling Point:242.8 °C at 760 mmHg
- PKA:pK1:3.385(+1) (25°C)
- Flash Point:99.4 °C
- PSA:26.02000
- Density:1.18 g/cm3
- LogP:2.81180
4-Chloro-2-methylaniline(Cas 95-69-2) Usage
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Air & Water Reactions |
May be sensitive to prolonged exposure to air and light. Insoluble in water. |
|
Reactivity Profile |
4-Chloro-2-methylaniline is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents. . A halogenated amine. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. |
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Hazard |
Toxic by ingestion and inhalation. Probable carcinogen. |
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Health Hazard |
Inhalation, ingestion, or skin contact causes bluish tint in fingernails, lips, and ears. Headache, drowsiness, and nausea also occur. Contact with eyes causes irritation. |
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Fire Hazard |
Special Hazards of Combustion Products: Toxic oxides of nitrogen and hydrochloric acid fumes may form. |
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Safety Profile |
Confirmed carcinogen. Poison by ingestion and subcutaneous routes. Human mutation data reported. In the presence of copperpI) chloride catalyst decomposition occurs above 239'C. When heated to decomposition it emits toxic fumes of Cland NOx. See also other chloro toluidme entries. |
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Potential Exposure |
Most of the isomers are used in dyestuff manufacture. The 3-chloro-para isomer is used to kill birds. It is marketed as pelleted bait for control of bird populations. |
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Shipping |
UN2239 Chlorotoluidines, solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3429 Chlorotoluidines, liquid, Hazard Class: 6.1; Labels: 6.1- Poisonous materials |
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Incompatibilities |
Incompatible with oxidizers, strong acids; chloroformates, and acid anhydrides, isocyanates, aldehydes forming fire and explosive hazards. |
|
General Description |
Gray to white solid with a weak fishy odor. Sinks in water. Freezing point is 77°F. |
InChI:InChI=1/C7H8ClN/c1-5-4-6(8)2-3-7(5)9/h2-4H,9H2,1H3
95-69-2 Relevant articles
METHOD OF REDUCING AROMATIC NITRO COMPOUNDS
-
Paragraph 0328, (2022/02/26)
A method for reducing a substrate select...
Method for synthesizing P-chloroO-toluidine
-
, (2021/10/05)
The invention discloses a method for syn...
High yielding electrophilic amination with lower order and?higher order organocuprates: Application of acetone O-(4-Chlorophenylsulfonyl)oxime in the construction of the C?N bond at room temperature
Duran, Serdar,Korkmaz, Adem
, p. 2077 - 2087 (2021/05/27)
Electrophilic amination reaction was per...
Room-temperature copper-catalyzed electrophilic amination of arylcadmium iodides with ketoximes
Korkmaz, Adem
, p. 3119 - 3125 (2021/05/10)
We started our study by preparation two ...
95-69-2 Process route
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24251-12-5
tertiary amyl hypochlorite
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-
584-70-3
N-benzoyl-2-methylaniline
-
-
95-69-2
4-chloro-2-methylbenzeneamine
| Conditions | Yield |
|---|---|
|
With
tetrachloromethane;
|
-
-
56-23-5
tetrachloromethane
-
-
24251-12-5
tertiary amyl hypochlorite
-
-
34143-86-7
N-((E)-benzylidene)-o-toluidine
-
-
584-70-3
N-benzoyl-2-methylaniline
-
-
95-69-2
4-chloro-2-methylbenzeneamine
| Conditions | Yield |
|---|---|
|
Erwaermen des Reaktionsprodukts mit wss.Schwefelsaeure;
|
95-69-2 Upstream products
-
56-23-5
tetrachloromethane
-
24251-12-5
tertiary amyl hypochlorite
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34143-86-7
N-((E)-benzylidene)-o-toluidine
-
31656-92-5
1-azido-2-methyl-benzene
95-69-2 Downstream products
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63320-86-5
Maleinsaeure-(4-chlor-2-methyl-anilid)
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20139-55-3
N-(2-methyl-4-chlorophenyl)-3-oxobutanamide
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61495-07-6
N-(4-chloro-2-methylphenyl)benzamide
-
5202-86-8
4-chloro-2-methylacetanilide
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1-Methyl-3-octylimidazolium chloride
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-
2-Chlorobenzoic acid
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-
9-(1-Naphthyl) carbazole
CAS:22034-43-1

