174899-82-2
- Product Name：1-ethyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide
- Molecular Formula：C8H11F6N3O4S2
- Purity：99%
- Molecular Weight：391.315
Product Details;
CasNo： 174899-82-2
Molecular Formula： C8H11F6N3O4S2
factory and manufacture 174899-82-2 1-ethyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide lonic liquid
- Molecular Formula:C8H11F6N3O4S2
- Molecular Weight:391.315
- Vapor Pressure:0.004-0.007Pa at 140.9-150.9℃
- Melting Point:≥−15 °C(lit.)
- Refractive Index:1.4220-1.4260
- Boiling Point:190.5 °C at 760 mmHg
- Flash Point:69 °C
- PSA：93.85000
- Density:1,53 g/cm3
- LogP:3.55340
1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE, 99% [EMIIM](Cas 174899-82-2) Usage
|
Referrence |
Schilderman, A. M.; Raeissi, S.; Peters, C. J., Solubility of carbon dioxide in the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. Fluid Phase Equilib. 2007, 260, 19-22. Buzzeo, M. C.; Klymenko, O. V.; Wadhawan, J. D.; Hardacre, C.; Seddon, K. R.; Compton, R. G., Voltammetry of oxygen in the room-temperature ionic liquids 1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide and hexyltriethylammonium bis((trifluoromethyl)sulfonyl)imide: One-electron reduction to form superoxide. Steady-state and transient behavior in the same cyclic voltammogram resulting from widely different diffusion coefficients of oxygen and superoxide. J. Phys. Chem. A 2003, 107, 8872-8878. Giovanelli, D.; Buzzeo, M. C.; Lawrence, N. S.; Hardacre, C.; Seddon, K. R.; Compton, R. G., Determination of ammonia based on the electro-oxidation of hydroquinone in dimethylformamide or in the room temperature ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. Talanta 2004, 62, 904-911. Goharshadi, E. K.; Ding, Y.; Nancarrow, P., Green synthesis of ZnO nanoparticles in a room-temperature ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. J. Phys. Chem. Solids 2008, 69, 2057-2060. |
|
Conductivity |
6.63 mS/cm |
|
General Description |
1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [EMIM][N(Tf)2] is a room temperature ionic liquid (RTIL). ([EMIM][N(Tf)2]) as a non-aqueous solvent, is advantageous over traditional aprotic polar organic solvents in electrochemical investigation of electroactive species since it has low vapor pressure, high thermal stability, good conductivity and a wide electrochemical window. [EMIM][N(Tf)2] shows good solubility in CO2. |
InChI:InChI=1/C6H11N2.C2F6NO4S2/c1-3-8-5-4-7(2)6-8;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h4-6H,3H2,1-2H3;/q+1;-1
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174899-82-2 Process route
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65039-09-0
1-ethyl-3-methyl-1H-imidazol-3-ium chloride
-
-
90076-65-6
bis(trifluoromethane)sulfonimide lithium
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174899-82-2
1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide
| Conditions | Yield |
|---|---|
|
In
acetonitrile;
at 20 ℃;
for 48h;
|
62% |
|
In
water;
at 25 ℃;
for 3h;
|
|
|
In
water;
at 20 ℃;
for 24h;
|
|
|
In
water;
|
|
|
In
acetone;
at 20 ℃;
for 24h;
|
|
|
In
water;
Ionic liquid;
|
|
|
In
dichloromethane; water;
|
|
|
In
dichloromethane; water;
|
-
-
1-ethyl-3-methylimidazolium bromide
-
-
174899-82-2
1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide
| Conditions | Yield |
|---|---|
|
With
bis(trifluoromethane)sulfonimide lithium;
In
acetone;
for 24h;
|
95% |
174899-82-2 Upstream products
-
7098-07-9
N-Ethylimidazole
-
537031-78-0
N-methyl bis[(trifluoromethyl)sulfonyl]imide
-
65039-08-9
3-ethyl-1-methyl-1H-imidazol-3-ium bromide
-
90076-65-6
bis(trifluoromethane)sulfonimide lithium
174899-82-2 Downstream products
-
951026-20-3
(1-ethyl-3-methylimidazolium )[Co(trimesate)]
-
1422393-56-3
[1-ethyl-3-methylmimdazolium][Ag(bis(trifluoromethanesulfonyl)imido)2]
-
1121-07-9
N-methylsuccinimide
-
2314-78-5
N-ethylsuccinimide
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-
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