4731-65-1
- Product Name：Tris(2-methoxyphenyl)phosphine
- Molecular Formula：C21H21O3P
- Purity：99%
- Molecular Weight：352.37
Product Details;
CasNo： 4731-65-1
Molecular Formula： C21H21O3P
Appearance： white powder or crystals
factory and supplier 4731-65-1 Tris(2-methoxyphenyl)phosphine in stock
- Molecular Formula:C21H21O3P
- Molecular Weight:352.37
- Appearance/Colour:white powder or crystals
- Vapor Pressure:8.19E-09mmHg at 25°C
- Melting Point:204-208 °C
- Boiling Point:477.3 °C at 760 mmHg
- Flash Point:302.5 °C
- PSA：41.28000
- LogP:3.47060
TRIS(2-METHOXYPHENYL)PHOSPHINE(Cas 4731-65-1) Usage
InChI:InChI=1/C21H21O3P/c1-22-16-10-4-7-13-19(16)25(20-14-8-5-11-17(20)23-2)21-15-9-6-12-18(21)24-3/h4-15H,1-3H3
4731-65-1 Relevant articles
Photochemical transformation of chlorobenzenes and white phosphorus into arylphosphines and phosphonium salts
Gschwind, Ruth M.,Mende, Michael,Scott, Daniel J.,Streitferdt, Verena,Till, Marion,Wolf, Robert
supporting information, p. 1100 - 1103 (2022/02/03)
Chlorobenzenes are important starting ma...
Photocatalytic Arylation of P4 and PH3: Reaction Development Through Mechanistic Insight
Cammarata, Jose,Gschwind, Ruth M.,Lennert, Ulrich,Rothfelder, Robin,Scott, Daniel J.,Streitferdt, Verena,Wolf, Robert,Zeitler, Kirsten
supporting information, p. 24650 - 24658 (2021/10/14)
Detailed 31P{1H} NMR spectroscopic inves...
A Lewis Base Nucleofugality Parameter, NFB, and Its Application in an Analysis of MIDA-Boronate Hydrolysis Kinetics
García-Domínguez, Andrés,Gonzalez, Jorge A.,Leach, Andrew G.,Lloyd-Jones, Guy C.,Nichol, Gary S.,Taylor, Nicholas P.
supporting information, (2022/01/04)
The kinetics of quinuclidine displacemen...
Versatile Visible-Light-Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts
Arockiam, Percia Beatrice,Lennert, Ulrich,Graf, Christina,Rothfelder, Robin,Scott, Daniel J.,Fischer, Tillmann G.,Zeitler, Kirsten,Wolf, Robert
supporting information, p. 16374 - 16382 (2020/11/03)
Asymmetrically substituted tertiary phos...
4731-65-1 Process route
-
-
578-57-4
2-bromoanisole
-
-
4731-65-1
tris(o-methoxyphenyl)phosphine
| Conditions | Yield |
|---|---|
|
With
phosphorus trichloride;
|
|
|
2-bromoanisole;
With
magnesium;
In
tetrahydrofuran;
With
phosphorus trichloride;
|
|
|
2-bromoanisole;
With
magnesium;
In
tetrahydrofuran;
for 2h;
Reflux;
With
phosphorus trichloride;
In
tetrahydrofuran;
at -78 ℃;
for 2h;
|
-
-
529-28-2
4-iodoanisol
-
-
4731-65-1
tris(o-methoxyphenyl)phosphine
| Conditions | Yield |
|---|---|
|
With
white phosphorus; 1,3-dicyano-5-fluoro-2,4,6-tris(diphenylamino)benzene; triethylamine;
In
acetonitrile; benzene;
for 24h;
Inert atmosphere;
Glovebox;
Sealed tube;
Irradiation;
|
12% |
|
With
dihydrogen phosphide sodium; (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; triethylamine;
In
acetonitrile;
at 20 ℃;
for 24h;
Reagent/catalyst;
Sealed tube;
Irradiation;
Schlenk technique;
Glovebox;
Inert atmosphere;
|
4731-65-1 Upstream products
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4-methoxyphenyl magnesium bromide
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methoxybenzene
-
31600-86-9
2-methoxyphenyllithium
-
578-57-4
2-bromoanisole
4731-65-1 Downstream products
-
10177-79-4
bis(2-methoxyphenyl)phosphine
-
118854-40-3
sodium di(2-methoxyphenyl)phosphide
-
103661-67-2
Tris(o-methoxyphenyl) selenide
-
123317-11-3
Tris(o-methoxyphenyl) sulfide
Relevant Products
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Cytidine 5'-monophosphate disodium saltCAS：6757-06-8
-
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-
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