32673-25-9
- Product Name：Di-tert-butylphenylphosphine
- Molecular Formula：C14H23P
- Purity：99%
- Molecular Weight：222.31
Product Details;
CasNo： 32673-25-9
Molecular Formula： C14H23P
factory and supplier 32673-25-9 Di-tert-butylphenylphosphine in stock
- Molecular Formula:C14H23P
- Molecular Weight:222.31
- Vapor Pressure:0.00457mmHg at 25°C
- Refractive Index:n20/D 1.5382
- Boiling Point:286.4 °C at 760 mmHg
- Flash Point:132 °C
- PSA：13.59000
- Density:0.933 g/mL at 25 °C
- LogP:4.39080
DI-TERT-BUTYLPHENYLPHOSPHINE(Cas 32673-25-9) Usage
InChI:InChI=1/C14H23P/c1-13(2,3)15(14(4,5)6)12-10-8-7-9-11-12/h7-11H,1-6H3
32673-25-9 Relevant articles
A Lewis Base Nucleofugality Parameter, NFB, and Its Application in an Analysis of MIDA-Boronate Hydrolysis Kinetics
Taylor, Nicholas P.,Gonzalez, Jorge A.,Nichol, Gary S.,García-Domínguez, Andrés,Leach, Andrew G.,Lloyd-Jones, Guy C.
supporting information, p. 721 - 729 (2022/01/04)
The kinetics of quinuclidine displacemen...
Generation of Phosphonium Sites on Sulfated Zirconium Oxide: Relationship to Br?nsted Acid Strength of Surface -OH Sites
Rodriguez, Jessica,Culver, Damien B.,Conley, Matthew P.
supporting information, p. 1484 - 1488 (2019/01/25)
The reaction of (tBu)2ArP (1a-h), where ...
A preparation method of compound phosphine benzene apperception (by machine translation)
-
Paragraph 0058; 0059; 0060; 0061, (2016/11/14)
The invention relates to a method for pr...
General and selective copper-catalyzed reduction of tertiary and secondary phosphine oxides: Convenient synthesis of phosphines
Li, Yuehui,Das, Shoubhik,Zhou, Shaolin,Junge, Kathrin,Beller, Matthias
supporting information; experimental part, p. 9727 - 9732 (2012/07/14)
Novel catalytic reductions of tertiary a...
32673-25-9 Process route
-
-
108-86-1,52753-63-6
bromobenzene
-
-
13716-10-4
di(tert-butyl)chlorophosphine
-
-
32673-25-9
di(tertbutyl)phenylphosphine
| Conditions | Yield |
|---|---|
|
bromobenzene;
With
magnesium;
In
tetrahydrofuran;
for 2h;
Inert atmosphere;
Reflux;
di(tert-butyl)chlorophosphine;
With
tetrakis(triphenylphosphine) palladium(0);
In
tetrahydrofuran;
at 20 ℃;
for 3h;
Reflux;
Inert atmosphere;
|
94.7% |
|
With
tert.-butyl lithium;
In
diethyl ether;
1.) -40 deg C, 2.) r.t. to reflux;
|
-
-
677-22-5
tert-butylmagnesium chloride
-
-
644-97-3
Dichlorophenylphosphine
-
-
32673-25-9
di(tertbutyl)phenylphosphine
| Conditions | Yield |
|---|---|
|
With
lithium bromide;
copper(l) iodide;
In
diethyl ether; hexane;
at -20 - 20 ℃;
for 3.5h;
|
71% |
|
With
lithium bromide;
copper(l) iodide;
In
diethyl ether; toluene;
at 20 ℃;
for 0.5h;
Product distribution / selectivity;
|
93.1 %Spectr. |
|
With
lithium bromide;
copper(l) iodide;
In
1,4-dioxane; diethyl ether;
at 20 ℃;
for 0.5h;
Product distribution / selectivity;
|
91.7 %Spectr. |
|
With
lithium bromide;
copper(l) iodide;
In
diethyl ether; hexane;
at 20 ℃;
for 0.5h;
Product distribution / selectivity;
|
98.7 %Spectr. |
|
With
lithium bromide;
copper(l) iodide;
In
diethyl ether; hexane;
at 20 ℃;
for 0.5 - 3.5h;
Quantum yield;
|
61 - 94.6 %Spectr. |
|
With
lithium bromide;
copper(l) iodide;
In
diethyl ether; hexane;
at -40 - 50 ℃;
for 1.83333h;
Kinetics;
|
6 - 95.8 %Spectr. |
|
With
lithium bromide;
copper(I) bromide dimethyl sulphide complex;
In
diethyl ether; hexane;
at -40 - 40 ℃;
for 0.5h;
Kinetics;
|
90.4 - 95 %Spectr. |
|
With
lithium bromide;
copper(I) bromide dimethyl sulphide complex;
In
diethyl ether; hexane;
at 20 ℃;
for 1 - 2h;
Quantum yield;
|
88 - 90 %Spectr. |
32673-25-9 Upstream products
-
108-86-1
bromobenzene
-
13716-10-4
di(tert-butyl)chlorophosphine
-
594-19-4
tert.-butyl lithium
-
644-97-3
Dichlorophenylphosphine
32673-25-9 Downstream products
-
6002-31-9
t-butylphenylphosphine
-
85617-56-7
bis(tert-butyl)phenylphosphine oxide
-
998-40-3
tributylphosphine
-
6476-37-5
dicyclohexylphenylphosphine
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-
O-ToluidineCAS：95-53-4
