934-72-5
- Product Name：Methyl p-tolyl sulfoxide
- Molecular Formula：C8H10 O S
- Purity：99%
- Molecular Weight：154.233
Product Details;
CasNo： 934-72-5
Molecular Formula： C8H10 O S
factory and supplier 934-72-5 Methyl p-tolyl sulfoxide in stock
- Molecular Formula:C8H10 O S
- Molecular Weight:154.233
- Melting Point:44-46 °C(lit.)
- Refractive Index:1.5780 (estimate)
- Boiling Point:113-114 °C2 mm Hg(lit.)
- Flash Point:124.6°C
- PSA：36.28000
- Density:1.15g/cm3
- LogP:2.59810
1-METHYL-4-(METHYLSULFINYL)BENZENE(Cas 934-72-5) Usage
|
Synthesis Reference(s) |
Chemistry Letters, 15, p. 967, 1986Synthetic Communications, 19, p. 1569, 1989 DOI: 10.1080/00397918908051052Tetrahedron Letters, 19, p. 3415, 1978 |
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General Description |
Methyl p-tolyl sulfoxide (MTSO), an alkyl-substituted p-tolyl sulfoxide, is a Lewis base. It behaves as an activator of silicon tetrachloride that is employed in aza-Diels-Alder reaction. |
InChI:InChI=1S/C8H10OS/c1-7-3-5-8(6-4-7)10(2)9/h3-6H,1-2H3
934-72-5 Relevant articles
Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives
Bulman Page, Philip C.,Vahedi, Hooshang,Bethell, Donald,Barkley, James V.
, p. 1937 - 1941 (2003)
DBU attacks saccharin derivatives with s...
Synergistic cooperative effect of CF3SO2Na and bis(2-butoxyethyl)ether towards selective oxygenation of sulfides with molecular oxygen under visible-light irradiation
Liu, Kai-Jian,Wang, Zheng,Lu, Ling-Hui,Chen, Jin-Yang,Zeng, Fei,Lin, Ying-Wu,Cao, Zhong,Yu, Xianyong,He, Wei-Min
supporting information, p. 496 - 500 (2021/01/28)
A safe, practical and eco-friendly metho...
Niobium(V) oxido tris-carbamate as easily available and robust catalytic precursor for the selective sulfide to sulfone oxidation
Bresciani, Giulio,Ciancaleoni, Gianluca,Crucianelli, Marcello,Gemmiti, Mario,Marchetti, Fabio,Pampaloni, Guido
, (2021/11/01)
The oxidation of the sulfide function pr...
Synthesis of a light-harvesting ruthenium porphyrin complex substituted with BODIPY units. Implications for visible light-promoted catalytic oxidations
Malone, Jonathan,Klaine, Seth,Alcantar, Christian,Bratcher, Fox,Zhang, Rui
, p. 4977 - 4985 (2021/03/26)
A light-harvesting ruthenium porphyrin s...
Air atmospheric photocatalytic oxidation by ultrathin C,N-TiO2nanosheets
Cheng, Xiuyan,Zhang, Jianling,Liu, Lifei,Zheng, Lirong,Zhang, Fanyu,Duan, Ran,Sha, Yufei,Su, Zhuizhui,Xie, Fei
supporting information, p. 1165 - 1170 (2021/02/26)
Herein, we demonstrate the highly effici...
934-72-5 Process route
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-
623-13-2
4-methylphenyl methylsulfide
-
-
536-57-2
p-toluene sulfinic acid
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-
934-72-5
Methyl p-tolyl sulfoxide
| Conditions | Yield |
|---|---|
|
With
oxygen;
In
dichloromethane;
Solvent;
Irradiation;
|
-
-
67-68-5,8070-53-9
dimethyl sulfoxide
-
-
106-45-6
para-thiocresol
-
-
623-13-2
4-methylphenyl methylsulfide
-
-
934-72-5
Methyl p-tolyl sulfoxide
-
-
103-19-5
di(p-tolyl) disulfide
| Conditions | Yield |
|---|---|
|
With
ammonium perchlorate; dihydrogen peroxide; iron(II) chloride;
In
water;
at 20 ℃;
for 7.5h;
|
19% 6% 61% |
934-72-5 Upstream products
-
623-13-2
4-methylphenyl methylsulfide
-
859940-71-9
dibromo-methyl-p-tolyl-λ4-sulfane
-
73475-07-7
isoaalloxazine hydroperoxide
-
75-77-4
chloro-trimethyl-silane
934-72-5 Downstream products
-
859940-71-9
dibromo-methyl-p-tolyl-λ4-sulfane
-
13372-58-2
N-(N'-butyl-carbamoyl)-methyl-(4-tolyl)-sulfoxim
-
4235-12-5
C15H17NO2S2
-
24824-93-9
chloromethyl p-tolyl sulfoxide
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