14126-37-5

  • Product Name:Dibromobis(triphenylphosphine)nickel(II)
  • Molecular Formula:C36H30Br2NiP2
  • Purity:99%
  • Molecular Weight:743.08
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Product Details;

CasNo: 14126-37-5

Molecular Formula: C36H30Br2NiP2

Appearance: dark green crystalline powder or crystals

factory and supplier 14126-37-5 Dibromobis(triphenylphosphine)nickel(II) in stock

  • Molecular Formula:C36H30Br2NiP2
  • Molecular Weight:743.08
  • Appearance/Colour:dark green crystalline powder or crystals 
  • Vapor Pressure:4.74E-05mmHg at 25°C 
  • Melting Point:219-223 °C(lit.) 
  • Boiling Point:360 °C at 760 mmHg 
  • Flash Point:181.7 °C 
  • PSA:27.18000 
  • LogP:8.58080 

BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE(Cas 14126-37-5) Usage

InChI:InChI=1/2C18H15P.2BrH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

14126-37-5 Relevant articles

Catalysis of Cross-Coupling and Homocoupling Reactions of Aryl Halides Utilizing Ni(0), Ni(I), and Ni(II) Precursors; Ni(0) Compounds as the Probable Catalytic Species but Ni(I) Compounds as Intermediates and Products

Manzoor, Adeela,Wienefeld, Patrick,Baird, Michael C.,Budzelaar, Peter H.M.

, p. 3508 - 3519 (2017/10/03)

Both Ni(0) and Ni(I) compounds are belie...

Specific features of nickel-catalyzed synthesis of poly(butyl (meth)acrylates)

Grishin,Valetova,Il'Ichev

, p. 1965 - 1969 (2012/03/12)

The activity of the catalytic system NiB...

LINEAR PYRIDAZINE AND PYRROLE COMPOUNDS, METHOD FOR OBTAINING THEM AND APPLICATIONS

-

Page/Page column 32, (2010/02/16)

The present invention relates to linear ...

Synthesis of 2-(N-arylimino-κN-methyl)pyrrolide-κN complexes of nickel

Pérez-Puente, Pilar,de Jesús, Ernesto,Flores, Juan C.,Gómez-Sal, Pilar

, p. 3902 - 3906 (2009/04/06)

2-(N-aryliminomethyl)pyrrole precursors ...

14126-37-5 Process route

((C<sub>6</sub>H<sub>5</sub>)3P)3Ni(H)Br
57584-08-4

((C6H5)3P)3Ni(H)Br

dibromobis(triphenylphosphine)nickel(II)
36673-36-6,111408-20-9,14126-37-5,54053-52-0

dibromobis(triphenylphosphine)nickel(II)

bis(triphenylphosphine)nickel<sup>(0)</sup> dicarbonyl
13007-90-4

bis(triphenylphosphine)nickel(0) dicarbonyl

Conditions
Conditions Yield
With carbon monoxide; In tetrahydrofuran; byproducts: (C6H5)3P; (Ar), to nickel complex added THF previously saturated with CO, CO passed in for 2.5 h at -20°C, pptd.; ppt. after washing (THF, pentane) obtained (Ph3P)2NiBr2, filtrate evaptd., washed (pentane) extracted (ether), chromy (Al2O3, benzene/petroleumether 1:1), elem. anal., IR;
nickel(II) bromide monohydrate

nickel(II) bromide monohydrate

triphenylphosphine
603-35-0

triphenylphosphine

dibromobis(triphenylphosphine)nickel(II)
36673-36-6,111408-20-9,14126-37-5,54053-52-0

dibromobis(triphenylphosphine)nickel(II)

Conditions
Conditions Yield
In butan-1-ol; at 20 ℃; Reflux;
60%

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