97239-80-0
- Product Name：1,1'-Bis(diisopropylphosphino)ferrocene
- Molecular Formula：C22H36FeP2
- Purity：99%
- Molecular Weight：418.322
Product Details;
CasNo： 97239-80-0
Molecular Formula： C22H36FeP2
Appearance： orange crystalline powder
factory and supplier 97239-80-0 1,1'-Bis(diisopropylphosphino)ferrocene in stock
- Molecular Formula:C22H36FeP2
- Molecular Weight:418.322
- Appearance/Colour:orange crystalline powder
- Melting Point:50-52 °C(lit.)
- Flash Point:>230°F
- PSA：27.18000
- LogP:6.72050
97239-80-0 Relevant articles
Diphosphanylmetallocenes of Main-Group Elements
Müller, Carsten,Warken, Joshua,Huch, Volker,Morgenstern, Bernd,Bischoff, Inga-Alexandra,Zimmer, Michael,Sch?fer, André
supporting information, p. 6500 - 6510 (2021/03/16)
Several 1,1′-diphosphanyl-substituted me...
A ferrocene diphosphine ligand preparation method
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Paragraph 0006; 0019; 0020, (2017/08/31)
The invention discloses a method for pre...
Bidentate ferrocenylphosphines and their palladium(II)dichloride complexes - X-ray structural and NMR spectroscopic investigations and first results of their characteristics in the Pd-catalysed cooligomerisation of 1,3-butadiene with CO2
Elsagir, Anja R.,Ga?ner, Franz,G?rls, Helmar,Dinjus, Eckhard
, p. 139 - 145 (2007/10/03)
The chiral 1,1′-bis(di(+)-menthylphosphi...
97239-80-0 Process route
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1,1'-bis(diisopropylphosphino)ferrocene tetrafluoroborate
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97239-80-0
1,1'-bis(diisopropylphosphino)ferrocene
| Conditions | Yield |
|---|---|
|
In
methanol;
for 12h;
Reflux;
|
90% |
-
-
1,1'-dilithioferrocene N,N,N'N'-tetramethylethylenediamine
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40244-90-4
Chlorodiisopropylphosphane
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-
97239-80-0
1,1'-bis(diisopropylphosphino)ferrocene
| Conditions | Yield |
|---|---|
|
In
hexane;
phosphine (2 equiv.) added dropwise at -78°C to Fe complex suspn., stirred for 30 min, warmed slowly to 20°C; hydrolyzed (H2O), org. layer sepd., dried (Na2SO4), solvent removed (vac.), crystd. at 5°C for hours; elem. anal.;
|
58% |
|
In
diethyl ether;
byproducts: bis(di-isopropylferrocenyl)phosphine; under inert gas, dropwise addn. of chlorophosphine to the stirred suspn. of ferrocene in diethyl ether, allowed to warm slowly to room temp., refluxed for 30 min, cooled, if excess phosphine, mixt. hydrolized, addn.of NaHCO3; filtered, concd. to oil, TLC, chromy. under N2 (hexane/diethyl ether-neutral alumina), major yellow fraction collected, concd., crystd. from hexane (slowly on standing), if excess phosphine, extd. with Et2O, dried over CaCl2; elem. anal.;
|
97239-80-0 Upstream products
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40244-90-4
Chlorodiisopropylphosphane
97239-80-0 Downstream products
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215788-65-1
dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II)
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460718-01-8
bromo(4-tert-butylphenyl)(1,1'-bis(di-isopropylphosphino)ferrocene)palladium
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167545-42-8
Ir(C8H12)(Fe(C5H4P(C3H7)2)2)(1+)*PF6(1-) = [Ir(C8H12)(Fe(C5H4P(C3H7)2)2)]PF6
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946828-75-7
((C6H5O)2PSN((CH3)2CH)2PC5H4)2Fe
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