16259-59-9
- Product Name：Benzene, 1,1'-(2,4-cyclopentadien-1-ylidenemethylene)bis[4-methyl-
- Molecular Formula：
- Purity：99%
- Molecular Weight：258.363
Product Details;
CasNo： 16259-59-9
factory and supplier 16259-59-9 Benzene, 1,1'-(2,4-cyclopentadien-1-ylidenemethylene)bis[4-methyl- in stock
- Molecular Formula:C20H18
- Molecular Weight:258.363
16259-59-9 Relevant articles
Visible-light-induced [4 + 2] cycloaddition of pentafulvenes by organic photoredox catalysis
Asada, Yosuke,Honda, Kiyoshi,Hoshino, Yujiro,Tanaka, Kenta
supporting information, p. 8074 - 8078 (2020/11/03)
We have developed thioxanthylium photore...
Method for producing fulvene
-
Paragraph 0038, (2017/03/08)
PROBLEM TO BE SOLVED: To provide a metho...
The bridged cyclopentadienyl indenyl (fluorenyl) zirconocene complexes for polyethylene macromonomers
Huang, Wenzhong,Li, Fengbo,Ma, Haiyan,Huang, Jiling
experimental part, p. 727 - 733 (2010/11/20)
The synthesis of long-chain branched pol...
FLUORENE DERIVATIVE, TRANSITION METAL COMPOUND, CATALYST FOR OLEFIN POLYMERIZATION, AND PROCESS FOR PRODUCING OLEFIN POLYMER
-
Page/Page column 64-66, (2008/06/13)
A novel fluorene derivative useful as a ...
16259-59-9 Process route
-
-
611-97-2
bis(p-methylphenyl)-methanone
-
-
542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene
-
-
16259-59-9
6,6’-di-p-tolylpentafulvene
| Conditions | Yield |
|---|---|
|
bis(p-methylphenyl)-methanone;
With
aluminum (III) chloride;
In
tetrahydrofuran;
at 20 ℃;
for 1h;
Inert atmosphere;
cyclopenta-1,3-diene;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at 20 ℃;
for 1h;
Inert atmosphere;
Schlenk technique;
|
90% |
|
cyclopenta-1,3-diene;
With
sodium hydride;
In
tetrahydrofuran;
at 0 ℃;
for 1h;
bis(p-methylphenyl)-methanone;
In
tetrahydrofuran;
at 0 ℃;
for 3h;
Reflux;
|
41% |
|
With
potassium hydroxide;
18-crown-6 ether;
In
tetrahydrofuran;
Ambient temperature;
|
30% |
|
With
sodium;
In
ethanol;
for 0.5h;
Heating;
|
|
|
With
methanol; sodium;
In
tetrahydrofuran;
|
-
-
611-97-2
bis(p-methylphenyl)-methanone
-
-
sodium cyclopentadienide
-
-
16259-59-9
6,6’-di-p-tolylpentafulvene
| Conditions | Yield |
|---|---|
|
In
tetrahydrofuran;
at 0 - 20 ℃;
for 144h;
|
74.5% |
|
bis(p-methylphenyl)-methanone; sodium cyclopentadienide;
In
tetrahydrofuran;
at 0 - 20 ℃;
for 144h;
With
hydrogenchloride;
In
diethyl ether; water;
|
74.5% |
|
In
tetrahydrofuran; diethyl ether;
at 20 ℃;
for 72h;
Inert atmosphere;
|
47.1% |
16259-59-9 Upstream products
-
611-97-2
bis(p-methylphenyl)-methanone
-
542-92-7
cyclopenta-1,3-diene
-
1141-08-8
4,4'-dimethylthiobenzophenone
16259-59-9 Downstream products
-
77669-75-1
1-(5-Di-p-tolylmethylene-cyclopenta-1,3-dienyl)-ethanone
-
443795-74-2
[(η(5)-C5H5)Ti(η(6)-C5H4=C(p-Tol)2)Cl]
-
443795-73-1
[(η(5)-C5Me5)Ti(η(6)-C5H4=C(p-Tol)2)Cl]
-
165822-95-7
[(1-4-η)-6,6-bis(4-methylphenyl)fulvene]methylbis(trimethylphosphine)cobalt(I)
Relevant Products
-
5-Bromo-m-xyleneCAS：556-96-7
-
3,6-Di terbutyl carbazoleCAS：37500-95-1
-
1H,1H,2H,2H-Perfluorohexyl iodideCAS：2043-55-2
-
2-Chloro-4-methylanilineCAS：615-65-6
