22426-14-8
- Product Name：2-Bromo-1,10-phenanthroline
- Molecular Formula：C12H7 Br N2
- Purity：99%
- Molecular Weight：259.105
Product Details;
CasNo： 22426-14-8
Molecular Formula： C12H7 Br N2
factory and supplier 22426-14-8 2-Bromo-1,10-phenanthroline in stock
- Molecular Formula:C12H7 Br N2
- Molecular Weight:259.105
- Melting Point:161.0 to 165.0 °C
- Boiling Point:414.3±25.0 °C(Predicted)
- PKA:4.20±0.10(Predicted)
- PSA：25.78000
- Density:1.616
- LogP:3.54550
2-Bromo-1,10-phenanthroline(Cas 22426-14-8) Usage
InChI:InChI=1/C12H7BrN2/c13-10-6-5-9-4-3-8-2-1-7-14-11(8)12(9)15-10/h1-7H
22426-14-8 Relevant articles
HYDROXYPHENYL PHENANTHROLINES AS POLYMERIZABLE BLOCKERS OF HIGH ENERGY LIGHT
-
Paragraph 0288; 0294, (2019/01/15)
Described are high energy light blocking...
A highly practical and convenient halogenation of fused heterocyclic N-oxides
Wang, Dong,Wang, Yuxi,Zhao, Junjie,Li, Linna,Miao, Longfei,Wang, Dong,Sun, Hua,Yu, Peng
, p. 5762 - 5768 (2016/08/30)
A novel, simple and practical method for...
Regioselective bromination of fused heterocyclic N-oxides
Wengryniuk, Sarah E.,Weickgenannt, Andreas,Reiher, Christopher,Strotman, Neil A.,Chen, Ke,Eastgate, Martin D.,Baran, Phil S.
supporting information, p. 792 - 795 (2013/04/10)
A mild method for the regioselective C2-...
Synthesis of new pyrrole-pyridine-based ligands using an in situ Suzuki coupling method
Boettger, Matthias,Wiegmann, Bjoern,Schaumburg, Steffen,Jones, Peter G.,Kowalsky, Wolfgang,Johannes, Hans-Hermann
, p. 1037 - 1047 (2012/08/28)
The compounds 6-(pyrrol-2-yl)-2,2'-bipyr...
22426-14-8 Process route
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31535-89-4
1-methyl-1,10-phenanthrolin-2(1H)-one
-
-
22426-14-8
2--bromo-1,10--phenanthroline
| Conditions | Yield |
|---|---|
|
1-methyl-1,10-phenanthrolin-2(1H)-one;
With
phosphorus pentabromide; phosphorus(V) oxybromide;
at 20 - 80 ℃;
Inert atmosphere;
With
ammonia;
In
water;
Alkaline conditions;
|
94% |
|
1-methyl-1,10-phenanthrolin-2(1H)-one;
With
phosphorus pentabromide; phosphorus(V) oxybromide;
at 80 ℃;
for 6h;
Inert atmosphere;
Cooling with ice;
With
ammonia;
In
water;
Cooling with ice;
|
94% |
|
With
bromine; triphenylphosphine;
In
acetonitrile;
at 0 ℃;
for 18h;
Reflux;
|
55% |
-
-
1891-19-6
1,10-phenanthroline N-oxide
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-
22426-14-8
2--bromo-1,10--phenanthroline
| Conditions | Yield |
|---|---|
|
1,10-phenanthroline N-oxide;
With
tetrabutylammomium bromide;
In
dichloromethane;
at 20 ℃;
for 0.166667h;
Inert atmosphere;
Molecular sieve;
With
p-toluenesulfonylanhydride;
In
dichloromethane;
at 20 ℃;
regioselective reaction;
Inert atmosphere;
|
70% |
|
With
N,N-dimethyl-formamide; phosphorus(V) oxybromide;
In
dichloromethane;
at 0 - 25 ℃;
regioselective reaction;
Inert atmosphere;
|
52% |
|
1,10-phenanthroline N-oxide;
With
tetrabutyl ammonium fluoride;
In
dichloromethane;
at 20 ℃;
for 0.166667h;
Molecular sieve;
With
p-toluenesulfonylanhydride;
In
dichloromethane;
at 20 ℃;
|
48% |
22426-14-8 Upstream products
-
66-71-7
1,10-Phenanthroline
-
31535-89-4
1-methyl-1,10-phenanthrolin-2(1H)-one
-
24721-92-4
1-Dimethylamino-ethanol
-
23647-26-9
1-methyl-1,10-phenanthrolinium iodide
22426-14-8 Downstream products
-
72404-92-3
2-acetyl-1,10-phenanthroline
-
39069-02-8
2,9-dibromo-1,10-phenanthroline
-
22426-17-1
2-phenoxy-1,10-phenanthroline
-
1181365-58-1
2-(3,5-diphenyl-1H-pyrazol-1-yl)-1,10-phenanthroline
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