174501-64-5
- Product Name：1-butyl-3-methylimidazolium hexafluorophosphate
- Molecular Formula：C8H15N2.PF6
- Purity：99%
- Molecular Weight：284.185
Product Details;
CasNo： 174501-64-5
Molecular Formula： C8H15N2.PF6
Appearance： Clear pale yellow oil
factory and manufacture 174501-64-5 1-butyl-3-methylimidazolium hexafluorophosphate lonic liquid
- Molecular Formula:C8H15N2.PF6
- Molecular Weight:284.185
- Appearance/Colour:Clear pale yellow oil
- Melting Point:6.5 °C
- Refractive Index:n20/D 1.41
- Boiling Point:>340°C
- Flash Point:>350°C
- PSA：22.40000
- Density:1.38 g/mL at 20 °C(lit.)
- LogP:4.49510
1-Butyl-3-methylimidazolium hexafluorophosphate(Cas 174501-64-5) Usage
|
Conductivity |
1.92 mS/cm |
|
General Description |
1-Butyl-3-methylimidazolium hexafluorophosphate is an imidazolium-based, hydrophobic, room temperature ionic liquid (RTIL). It can be prepared by reacting 1-methylimidazole with chlorobutane. Gaseous hydrofluorocarbons (HFCs) such as fluoromethane, fluoroethane and 1,1,2,2-tetrafluoroethane are soluble in BMIMPF6. |
InChI:InChI=1/C8H16N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-7H,3-5,8H2,1-2H3;/q;-1/p+1
174501-64-5 Relevant articles
High performance asymmetric supercapacitor based on MnO2 electrode in ionic liquid electrolyte
Zhang, Xuan,Zhao, Dandan,Zhao, Yongqing,Tang, Pengyi,Shen, Yinglin,Xu, Cailing,Li, Hulin,Xiao, Yu
, p. 3706 - 3712 (2013)
In this work, the electrochemical proper...
Examination of ionic liquids and their interaction with molecules, when used as stationary phases in gas chromatography
Armstrong, Daniel W.,He, Lingfeng,Liu, Yan-Song
, p. 3873 - 3876 (1999)
Stable room-temperature ionic liquids (R...
One-pot and solventless synthesis of ionic liquids under ultrasonic irradiation
Estager, Julien,Lévêque, Jean-Marc,Cravotto, Giancarlo,Boffa, Luisa,Bonrath, Werner,Draye, Micheline
, p. 2065 - 2068 (2007)
A novel method is described for the one-...
Association of ionic liquids in solution: Conductivity studies of [BMIM][Cl] and [BMIM][PF6] in binary mixtures of acetonitrile + methanol: Ion association in ionic liquid solutions
Jan, Roohi,Rather, Ghulam Mohammad,Bhat, Mohsin Ahmad
, p. 738 - 745 (2013)
The concentration dependence of molar co...
Effect of temperature on the purity of product in the preparation of 1-butyl-3-methylimidazolium-based ionic liquids
K?rkk?inen, Johanna,Asikkala, Janne,Laitinen, Risto S.,Lajunen, Marja K.
, p. 763 - 770 (2004)
The preparation of room-temperature ioni...
Liquid-liquid equilibria of room-temperature ionic liquids and butan-1-ol
Wu,Marsh, Kenneth N.,Deev, Alexander V.,Boxall, John A.
, p. 486 - 491 (2003)
Room-temperature ionic liquids are salts...
Spectroscopic and photophysical properties of ZnTPP in a room temperature ionic liquid
Szmytkowski, Jedrzej,Bond, Toby,Paige, Matthew F.,Scott, Robert W. J.,Steer, Ronald P.
, p. 11471 - 11476 (2010)
The steady-state absorption and emission...
A rationalization of the solvent effect on the Diels-Alder reaction in ionic liquids using multiparameter linear solvation energy relationships
Bini, Riccardo,Chiappe, Cinzia,Mestre, Veronica Llopsis,Pomelli, Christian Silvio,Welton, Thomas
, p. 2522 - 2529 (2008)
The Diels-Alder reaction between cyclope...
Preparation of second generation ionic liquids by efficient solvent-free alkylation of N-heterocycles with chloroalkanes
Cravotto, Giancarlo,Gaudino, Emanuela Calcio,Boffa, Luisa,Leveque, Jean-Marc,Estager, Julien,Bonrath, Werner
, p. 149 - 156 (2008)
Non-conventional techniques, such as mic...
Effect of ionic liquids on the conformation of a porphyrin-based viscometer
Jameson, Laramie P.,Kimball, Joseph D.,Gryczynski, Zygmunt,Balaz, Milan,Dzyuba, Sergei V.
, p. 18300 - 18304 (2013)
Structure of the cationic and anionic co...
Anthralin: Primary products of its redox reactions
Czerwinska, Malgorzata,Sikora, Adam,Szajerski, Piotr,Zielonka, Jacek,Adamus, Jan,Marcinek, Andrzej,Piech, Krzysztof,Bednarek, Pawel,Bally, Thomas
, p. 5312 - 5319 (2006)
One-electron reduction significantly enh...
Capillary electrophoretic application of 1-Alkyl-3-methylimidazolium-based ionic liquids
Yanes,Gratz,Baldwin,Robison,Stalcup
, p. 3838 - 3844 (2001)
Ionic substances with melting points at ...
Physicochemical properties and structures of room temperature ionic liquids. 1. Variation of anionic species
Tokuda, Hiroyuki,Hayamizu, Kikuko,Ishii, Kunikazu,Susan, Md. Abu Bin Hasan,Watanabe, Masayoshi
, p. 16593 - 16600 (2004)
Room-temperature ionic liquids (RTILs) b...
Thermal phase behavior of 1-butyl-3-methylimidazolium hexafluorophosphate: Simultaneous measurements of the melting of two polymorphic crystals by Raman spectroscopy and calorimetry
Endo, Takatsugu,Nishikawa, Keiko
, p. 79 - 82 (2013)
The thermal phase behavior of 1-butyl-3-...
Liquid-Crystalline Ionic Liquids as Ordered Reaction Media for the Diels–Alder Reaction
Bruce, Duncan W.,Gao, Yanan,Canongia Lopes, José Nuno,Shimizu, Karina,Slattery, John M.
, p. 16113 - 16123 (2016)
Liquid-crystalline ionic liquids (LCILs)...
18-crown-6 and dibenzo-18-crown-6 assisted extraction of cesium from water into room temperature ionic liquids and its correlation with stability constants for cesium complexes
Vendilo, Andrey G.,Djigailo, Dmitry I.,Smirnova, Svetlana V.,Torocheshnikova, Irina I.,Popov, Konstantin I.,Krasovsky, Vladimir G.,Pletnev, Igor V.
, p. 5001 - 5016 (2009)
The pH-profiles of the extraction of Cs+...
Controlling the reactions of 1-bromogalactose acetate in methanol using ionic liquids as co-solvents
Gilbert, Alyssa,Haines, Ronald S.,Harper, Jason B.
, p. 5442 - 5452 (2020)
The reactions of an acetobromogalactose ...
Understanding the effects of ionic liquids on a unimolecular substitution process: Correlating solvent parameters with reaction outcome
Gilbert, Alyssa,Haines, Ronald S.,Harper, Jason B.
, p. 675 - 682 (2019)
A unimolecular substitution process was ...
A general and direct synthesis of imidazolium ionic liquids using orthoesters
Kim, Do Joong,Oh, Kyung Hwan,Park, Jin Kyoon
, p. 4098 - 4101 (2014)
A general method to synthesize halide an...
X-ray Photoelectron Spectroscopy of Imidazolium-Based Zwitterions: The Intramolecular Charge-Transfer Effect
Shuang Men,Yujuan Jin
, p. 2337 - 2340 (2018)
Abstract: We investigate the imidazolium...
How to predict the physical properties of ionic liquids: A volume-based approach
Slattery, John M.,Daguenet, Corinne,Dyson, Paul J.,Schubert, Thomas J. S.,Krossing, Ingo
, p. 5384 - 5388 (2007)
(Chemical Equation Presented) The molecu...
Modelling catalytic turnover frequencies in ionic liquids: The determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-w-butyl-3- methylimidazolium hexafluorophosphate
Swiderski, Konrad,McLean, Andrew,Gordon, Charles M.,Vaughan
, p. 590 - 591 (2004)
The bimolecular rate constant for solven...
Ionic Liquids: Additives for Manipulating the Nucleophilicity
Rather, Mudasir Ahmad,Rather, Ghulam Mohammad,Pandit, Sarwar Ahmad,Bhat, Sajad Ahmad,Khan, Khaliquz Zaman,Bhat, Mohsin Ahmad
, p. 1518 - 1528 (2015)
Kinetic investigations of the SN2 reacti...
A Novel and Eco-friendly Method for the Preparation of Ionic Liquids
Xu, Dan-Qian,Liu, Bao-You,Luo, Shu-Ping,Xu, Zhen-Yuan,Shen, Yin-Chu
, p. 2626 - 2628 (2003)
A novel and eco-friendly method is descr...
Introduction of an ordered porous polymer network into a ceramic alumina membrane via non-hydrolytic sol-gel methodology for targeted dynamic separation
Meng, Minjia,Liu, Yan,Zhang, Min,Feng, Yonghai,Yan, Yongsheng
, p. 38630 - 38642 (2014)
A highly selective composite imprinted a...
A hybrid electrochemical-colorimetric sensing platform for detection of explosives
Forzani, Erica S.,Lu, Donglai,Leright, Matthew J.,Aguilar, Alvaro Diaz,Tsow, Francis,Lalesias, Rodriao A.,Lu, Jin,Tao, Nongjian,Zhang, Qian,Li, Jinghong
, p. 1390 - 1391 (2009)
-
Separation/preconcentration of trace copper by extraction into [C 4mim] [PF6] RITL containing p-tert-butyl-calix[4]arene functionalized with o-phenanthroline prior to flame absorption atomic spectrometry
Ma, Lina,Zhu, Xiashi,Wang, Wenjun
, p. 20 - 24 (2013)
A liquid-liquid extraction (LLE)-flame a...
A speedy one-pot synthesis of second-generation ionic liquids under ultrasound and/or microwave irradiation
Cravotto, Giancarlo,Boffa, Luisa,L'Eveque, Jean-Marc,Estager, Julien,Draye, Micheline,Bonrath, Werner
, p. 946 - 950 (2007)
The present work describes an efficient ...
Impregnation of different ionic liquids onto cationic starch and their comparison in the extraction of Th(IV)
Bursali, Elif Ant,Bozkurt, Serap Seyhan,Yurdako?, Mürüvvet
, p. 364 - 372 (2016)
Cationic starch (CS) was prepared by usi...
Solvatochromic probe behavior within ternary room-temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate + ethanol + water solutions
Fletcher, Kristin A.,Pandey, Siddharth
, p. 13532 - 13539 (2003)
The solvatochromic probe behavior within...
Do anions influence the polarity of protic ionic liquids?
Shukla, Shashi Kant,Khupse, Nageshwar D.,Kumar, Anil
, p. 2754 - 2761 (2012)
Polarity studies in two classes of imida...
Exploring physicochemical aspects of N-alkylimidazolium based ionic liquids
Bhat, Mohsin Ahmad,Dutta, Chanmeet K.,Rather, Ghulam Mohammad
, p. 142 - 151 (2013)
Physicochemical aspects (structural, the...
Simultaneous determination of Brilliant Green and Crystal Violet dyes in fish and water samples with dispersive liquid-liquid micro-extraction using ionic liquid followed by zero crossing first derivative spectrophotometric analysis method
Sadeghi, Susan,Nasehi, Zohreh
, p. 134 - 142 (2018)
In this study, dispersive liquid-liquid ...
Insights into water coordination associated with the CuII/ CuI electron transfer at a biomimetic Cu centre
Porras Gutierrez, Ana Gabriela,Zeitouny, Joceline,Gomila, Antoine,Douziech, Benedicte,Cosquer, Nathalie,Conan, Francoise,Reinaud, Olivia,Hapiot, Philippe,Le Mest, Yves,Lagrost, Corinne,Le Poul, Nicolas
, p. 6436 - 6445 (2014)
The coordination properties of the biomi...
Correlating ionic liquid solvent effects with solvent parameters for a reaction that proceeds through a xanthylium intermediate
Gilbert, Alyssa,Bucher, G?tz,Haines, Ronald S.,Harper, Jason B.
, p. 9336 - 9342 (2019)
A unimolecular nucleophilic substitution...
Chemoselective thioacetalization and transthioacetalization of carbonyl compounds catalyzed by immobilized scandium(III) triflate in ionic liquids
Kamal, Ahmed,Chouhan, Gagan
, p. 3337 - 3340 (2003)
Immobilized scandium triflate [Sc(OTf)3]...
Interactions of 1-butyl-3-methylimidazolium hexafluorophosphate with N,N-dimethylformamide: Density and viscosity measurements
Bennett,Dikio,Angaye,Wankasi,Dikio,Bahadur,Ebenso
, p. 661 - 666 (2016)
Physico-chemical properties: density (ρ)...
Temperature-dependent solvatochromic probe behavior within ionic liquids and (ionic liquid + water) mixtures
Trivedi, Shruti,Malek, Naved I.,Behera, Kamalakanta,Pandey, Siddharth
, p. 8118 - 8125 (2010)
Spectroscopic responses of absorbance pr...
Solvent-solute interactions in ionic liquids
Crowhurst, Lorna,Mawdsley, Philip R.,Perez-Arlandis, Juan M.,Salter, Paul A.,Welton, Tom
, p. 2790 - 2794 (2003)
A range of ionic liquids was studied uti...
Synthesis of Zn-based metal-organic frameworks in ionic liquid microemulsions at room temperature
Ye, Ranfeng,Ni, Min,Xu, Yuanyuan,Chen, Hao,Li, Shengqing
, p. 26237 - 26242 (2018)
For the first time, Zn-metal-organic fra...
Dynamic solvation in room-temperature ionic liquids
Chowdhury,Halder,Sanders,Calhoun,Anderson,Armstrong,Song,Petrich
, p. 10245 - 10255 (2004)
The dynamic solvation of the fluorescent...
Label-free polypeptide-based enzyme detection using a graphene-nanoparticle hybrid sensor
Myung, Sung,Yin, Perry T.,Kim, Cheoljin,Park, Jaesung,Solanki, Aniruddh,Reyes, Pavel Ivanoff,Lu, Yicheng,Kim, Kwang S.,Lee, Ki-Bum
, p. 6081 - 6087 (2012)
A graphene-nanoparticle (NP) hybrid bios...
Synthesis and physical-chemical properties of ionic liquids based on 1- n-butyl-3-methylimidazolium cation
Suarez,Einloft,Dullius,De Souza,Dupont
, p. 1626 - 1639 (1998)
The reaction of 1-n-butyl-3-methylimidaz...
Influence of structural variation in room-temperature ionic liquids on the selectivity and efficiency of competitive alkali metal salt extraction by a crown ether
Chun,Dzyuba,Bartsch
, p. 3737 - 3741 (2001)
An improved method for the preparation o...
Biosynthesis of glycyrrhetic acid 3-O-mono-β-d-glucuronide catalyzed by β-d-glucuronidase with enhanced bond selectivity in an ionic liquid/buffer biphasic system
He, Dong-Mei,Kaleem, Imdad,Qin, Si-Ying,Dai, Da-Zhang,Liu, Gui-Yan,Li, Chun
, p. 1916 - 1922 (2010)
The bond selective hydrolysis of glycyrr...
Thermodynamic investigation of room temperature ionic liquid : the heat capacity and thermodynamic functions of BMIPF6
Zhang, Z. H.,Zhang, J. L.,Xiong, H.,Li, G. P.,Cui, T.,Sun, L. X.,Xu, F.,Cao, Z.,Li, F.,Zhao, J. J.
, p. 1143 - 1148 (2010)
The molar heat capacities of the room te...
Convenient synthesis of various ionic liquids from onium hydroxides and ammonium salts
Peng, Yanqing,Li, Guiyun,Li, Jianguo,Yu, Shaojun
, p. 4286 - 4288 (2009)
Hydroxide ionic liquids, such as 1-alkyl...
Utilisation of 1,3-dialkylimidazolium-2-carboxylates as CO 2-carriers in the presence of Na+ and K+: Application in the synthesis of carboxylates, monomethylcarbonate anions and halogen-free ionic liquids
Tommasi, Immacolata,Sorrentino, Fabiana
, p. 2141 - 2145 (2005)
1,3-Dialkylimidazolium-2-carboxylate com...
Probing the importance of ionic liquid structure: A general ionic liquid effect on an SNAr process
Tanner, Eden E. L.,Hawker, Rebecca R.,Yau, Hon Man,Croft, Anna K.,Harper, Jason B.
, p. 7516 - 7521 (2013)
The effect of a range of ionic liquids, ...
Surface spectroscopy of room-temperature ionic liquids on a platinum electrode: A sum frequency generation study
Rivera-Rubero, Selimar,Baldelli, Steven
, p. 15133 - 15140 (2004)
Sum frequency generation vibrational spe...
β-Diimine-methallyl nickel complexes in ionic liquid: A biphasic green system for the high selective styrene dimerization
Landolsi, Kamel,Msaddek, Moncef
, (2022/02/23)
The selective head-to-tail dimerization ...
Red Propolis as a Source of Antimicrobial Phytochemicals: Extraction Using High-Performance Alternative Solvents
dos Santos, Cíntia M.,de Souza Mesquita, Leonardo M.,Braga, Anna Rafaela C.,de Rosso, Veridiana V.
, (2021/06/28)
Propolis is a resinous material rich in ...
Convenient synthesis of long alkyl-chain triazolylglycosides using ionic liquid as dual promoter-solvent: Readily access to non-ionic triazolylglycoside surfactants for evaluation of cytotoxic activity
Ketsomboon, Nutthanicha,Saeeng, Rungnapha,Sirion, Uthaiwan,Srisook, Klaokwan
, (2021/08/26)
A convenient method for the one-pot synt...
174501-64-5 Process route
-
-
616-47-7
1-methyl-1H-imidazole
-
-
109-65-9
1-bromo-butane
-
-
174501-64-5
3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate
| Conditions | Yield |
|---|---|
|
With
potassium hexafluorophosphate;
at 40 - 120 ℃;
for 0.166667h;
microwave irradiation; sonication;
|
94% |
|
With
potassium hexafluorophosphate;
at 80 ℃;
for 3.5h;
|
93% |
|
With
ammonium hexafluorophosphate; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate;
at 80 ℃;
for 15h;
|
89% |
|
1-methyl-1H-imidazole;
With
potassium hexafluorophosphate;
at 80 ℃;
for 12h;
1-bromo-butane;
In
water;
|
86% |
|
1-methyl-1H-imidazole; 1-bromo-butane;
at 140 ℃;
With
hexafluorophosphoric acid;
In
water;
for 0.166667h;
Further stages.;
|
64% |
|
With
potassium hexafluorophosphate;
In
water;
at 84 ℃;
for 3h;
sonification;
|
61% |
|
1-methyl-1H-imidazole; 1-bromo-butane;
In
toluene;
at 90 ℃;
for 2h;
With
hexafluorophosphoric acid;
In
water;
Further stages.;
|
-
-
85100-77-2
1-n-butyl-3-methylimidazolim bromide
-
-
174501-64-5
3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate
| Conditions | Yield |
|---|---|
|
With
potassium hexafluorophosphate;
In
water;
at 20 ℃;
|
100% |
|
With
ammonium hexafluorophosphate;
In
water;
at 20 ℃;
for 2h;
|
91% |
|
With
potassium hexafluorophosphate;
In
water;
at 20 ℃;
for 24h;
|
87% |
|
With
hexafluorophosphoric acid;
In
water;
|
79% |
|
With
potassium hexafluorophosphate;
In
dichloromethane;
for 48h;
|
78% |
|
With
ammonium hexafluorophosphate;
In
water;
at 20 ℃;
for 2h;
|
75% |
|
With
potassium hexafluorophosphate;
In
water;
at 20 ℃;
for 18h;
|
73% |
|
With
potassium hexafluorophosphate;
In
water;
at 20 ℃;
for 24h;
|
70% |
|
With
potassium hexafluorophosphate;
In
water;
at 20 ℃;
for 16h;
|
61% |
|
With
potassium hexafluorophosphate;
In
water;
at 20 ℃;
for 2h;
|
59% |
|
With
hexafluorophosphoric acid;
In
water;
at 20 ℃;
for 4h;
|
52% |
|
With
ammonium hexafluorophosphate;
|
|
|
With
hexafluorophosphoric acid;
In
water;
at 0 - 20 ℃;
for 2h;
|
1.58 mmol |
|
With
potassium hexafluorophosphate;
|
|
|
With
sodium hexaflorophosphate;
at 100 ℃;
for 0.25h;
Microwave irradiation;
Neat (no solvent);
|
|
|
With
potassium hexafluorophosphate;
at 20 ℃;
for 6h;
|
|
|
With
sodium hexaflorophosphate;
In
water;
|
|
|
With
potassium hexafluorophosphate;
at 20 ℃;
for 5h;
|
|
|
With
potassium hexafluorophosphate;
In
water;
at 80 ℃;
for 3h;
|
|
|
With
potassium hexafluorophosphate;
In
water;
|
|
|
With
potassium hexafluorophosphate;
|
|
|
With
potassium hexafluorophosphate;
In
methanol;
at 20 ℃;
for 2h;
|
|
|
With
potassium hexafluorophosphate;
In
acetone;
at 20 ℃;
for 2h;
|
|
|
With
potassium hexafluorophosphate;
In
acetone;
at 20 ℃;
for 2h;
|
|
|
With
potassium hexafluorophosphate;
In
water;
at 20 ℃;
for 24h;
|
|
|
With
hexafluorophosphoric acid;
In
acetone;
at 20 ℃;
for 24h;
|
|
|
With
potassium hexafluorophosphate;
In
acetone;
at 20 ℃;
for 2h;
|
|
|
With
potassium hexafluorophosphate;
In
acetone;
at 40 ℃;
for 10h;
|
|
|
With
potassium hexafluorophosphate;
Inert atmosphere;
|
174501-64-5 Upstream products
-
79917-90-1
1-butyl-3-methylimidazolium chloride
-
616-47-7
1-methyl-1H-imidazole
-
109-65-9
1-bromo-butane
-
109-69-3
n-Butyl chloride
174501-64-5 Downstream products
-
616-47-7
1-methyl-1H-imidazole
-
106-98-9
1-butylene
-
2366-52-1
1-fluorobutane
-
79973-42-5
bis(η5-pentamethylcyclopentadienyl)cobalt(III) hexafluorophosphate
Relevant Products
-
1-Ethyl-3-methylimidazolium hexafluorophosphateCAS：155371-19-0
-
1,4-Dibromo-2,5-difluorobenzeneCAS：327-51-5
-
2,3,4,5,6-Pentafluorobenzeneboronic acidCAS：1582-24-7
