98-56-6
- Product Name:4-Chlorobenzotrifluoride
- Molecular Formula:C7H4ClF3
- Purity:99%
- Molecular Weight:180.557
Product Details;
CasNo: 98-56-6
Molecular Formula: C7H4ClF3
Appearance: Clear colourless to light yellow liquid
factory and supplier 98-56-6 4-Chlorobenzotrifluoride in stock
- Molecular Formula:C7H4ClF3
- Molecular Weight:180.557
- Appearance/Colour:Clear colourless to light yellow liquid
- Vapor Pressure:0.0044mmHg at 25°C
- Melting Point:-36 °C(lit.)
- Refractive Index:1.4460
- Boiling Point:138.5 °C at 760 mmHg
- Flash Point:47.2 °C
- PSA:0.00000
- Density:1.338 g/cm3
- LogP:3.35880
4-Chlorobenzotrifluoride(Cas 98-56-6) Usage
|
Air & Water Reactions |
Highly flammable. Insoluble in water. |
|
Reactivity Profile |
4-Chlorobenzotrifluoride is sensitive to heat and light. 4-Chlorobenzotrifluoride reacts vigorously with oxidizing materials such as permanganates and dichromates. 4-Chlorobenzotrifluoride is incompatible with strong bases. 4-Chlorobenzotrifluoride is also incompatible with sodium dimethyl sulfonate. |
|
Fire Hazard |
4-Chlorobenzotrifluoride is combustible. |
|
Safety Profile |
Mildly toxic by ingestion and inhalation. Human mutation data reported. Flammable. Strongly exothermic reaction with sodium dimethylsulfinate. When heated to decomposition it emits toxic fumes of Fand Cl-. See also CHLORINATED HYDROCARBONS, AROMATIC; and FLUORIDES. |
|
Purification Methods |
Purify it as for o-chlorobenzotrifluoride above. [Beilstein 5 IV 815.] |
|
General Description |
Clear colorless liquid with an aromatic odor. |
InChI:InChI:1S/C7H4ClF3/c8-6-3-1-5(2-4-6)7(9,10)11/h1-4H
98-56-6 Relevant articles
Cross-Coupling through Ag(I)/Ag(III) Redox Manifold
Demonti, Luca,Mézailles, Nicolas,Nebra, Noel,Saffon-Merceron, Nathalie
supporting information, p. 15396 - 15405 (2021/10/12)
In ample variety of transformations, the...
Novel synthetic method of halogenated aromatic hydrocarbon
-
Paragraph 0017-0032, (2020/01/25)
The invention discloses a novel syntheti...
Ligand-free trifluoromethylation of iodoarenes by use of 2-Aryl-2-trifluoromethylbenzimidazoline as new trifluoromethylating reagent
Miyagawa, Masamichi,Ishikawa, Taisuke,Shinkai, Kota,Akiyama, Takahiko
supporting information, p. 29 - 31 (2019/01/04)
N-Methyl 2-aryl-2-trifluoromethylbenzimi...
Mechanism of Photoredox-Initiated C-C and C-N Bond Formation by Arylation of IPrAu(I)-CF3 and IPrAu(I)-Succinimide
Kim, Suhong,Toste, F. Dean
, p. 4308 - 4315 (2019/01/25)
Herein, we report on the photoredox-init...
98-56-6 Process route
-
-
110-91-8,99108-56-2
morpholine
-
-
320-60-5
2,4-dichloro-benzotrifluoride
-
-
4-(3-chloro-4-trifluoromethylphenyl)morpholine
-
-
98-56-6
4-chlorobenzotrifluoride
-
-
88-16-4
1-chloro-2-(trifluoromethyl)benzene
| Conditions | Yield |
|---|---|
|
With
Adipic acid; N'-phenyloxalyl bishydrazide; copper diacetate; sodium acetate; cetyltrimethylammonim bromide; 2,5-hexanedione; potassium hydroxide;
In
water;
at 110 ℃;
for 3h;
Inert atmosphere;
|
5% |
-
-
421-83-0
trifluoromethane sulfonyl chloride
-
-
108-90-7
chlorobenzene
-
-
98-56-6
4-chlorobenzotrifluoride
-
-
98-15-7
3-chlorotrifluoromethylbenzene
-
-
88-16-4
1-chloro-2-(trifluoromethyl)benzene
| Conditions | Yield |
|---|---|
|
With
N,N,N,N-tetraethylammonium tetrafluoroborate; triethylamine;
In
acetonitrile;
Overall yield = 35 percentSpectr.;
Electrochemical reaction;
|
98-56-6 Upstream products
-
5216-25-1
4-chlorotrichloromethylbenzene
-
455-14-1
4-trifluoromethylphenylamine
-
106-39-8
bromochlorobenzene
-
75-63-8
Bromotrifluoromethane
98-56-6 Downstream products
-
2366-92-9
1-ethoxy-4-(trifluoromethyl)benzene
-
402-52-8
methyl 4-(trifluoromethyl)phenyl ether
-
99-96-7
4-hydroxy-benzoic acid
-
90-98-2
4,4'-Dichlorobenzophenone
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