829-84-5
- Product Name:Dicyclohexylphosphine
- Molecular Formula:C12H23P
- Purity:99%
- Molecular Weight:198.288
Product Details;
CasNo: 829-84-5
Molecular Formula: C12H23P
Appearance: Colorless Liquid
factory and supplier 829-84-5 Dicyclohexylphosphine in stock
- Molecular Formula:C12H23P
- Molecular Weight:198.288
- Appearance/Colour:Colorless Liquid
- Vapor Pressure:0.00373mmHg at 25°C
- Melting Point:2°C
- Refractive Index:n 20/D 1.516
- Boiling Point:289.8 °C at 760 mmHg
- Flash Point:129.1 °C
- PSA:13.59000
- Density:0.98 g/cm3
- LogP:4.33030
DICYCLOHEXYLPHOSPHINE(Cas 829-84-5) Usage
|
General Description |
Dicyclohexylphosphine is a chemical compound with the molecular formula C12H23P. It is a white solid at room temperature and is commonly used as a ligand in organometallic chemistry. Dicyclohexylphosphine is a strong donor of electron density, and its bulky nature allows it to stabilize metal centers in catalytic reactions. It is also often used in the synthesis of various organometallic complexes and as a reducing agent in organic synthesis. Additionally, dicyclohexylphosphine has been studied for its potential use in pharmaceutical and medicinal applications, showing promise as a versatile building block in the preparation of new drugs. Overall, dicyclohexylphosphine plays a crucial role in the field of organometallic chemistry and has a wide range of applications in both academic research and industrial processes. |
InChI:InChI=1/C12H23P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h11-13H,1-10H2
829-84-5 Relevant articles
Copper-catalyzed C–P cross-coupling of secondary phosphines with (hetero)aromatic bromide
Li, Chun-Jing,Lü, Jing,Zhang, Zhi-Xun,Zhou, Kun,Li, Yan,Qi, Guang-Hui
, p. 4547 - 4562 (2018/04/20)
A novel and convenient approach to the s...
Rapid Metal-Free Formation of Free Phosphines from Phosphine Oxides
Provis-Evans, Cei B.,Emanuelsson, Emma A. C.,Webster, Ruth L.
supporting information, p. 3999 - 4004 (2018/09/21)
A rapid method for the reduction of seco...
Photo-initiator 2,4,6-trimethylbenzoyldicyclohexyloxyphosphine and preparation method and application thereof
-
Paragraph 0020; 0021, (2016/10/20)
The invention relates to a preparation m...
Phosphonium bis(glycolates) and phosphinoglycolates: Synthesis, solvolysis, oxidation to (thio)phosphinoylglycolates and use as ligands in Ni-catalyzed ethylene oligomerization
Peulecke, Normen,Kindermann, Markus K.,K?ckerling, Martin,Heinicke, Joachim
body text, p. 61 - 69 (2012/08/27)
Secondary phosphines, glyoxylic acid hyd...
829-84-5 Process route
-
-
14717-29-4
dicyclohexylphosphine oxide
-
-
829-84-5
dicyclohexylphosphane
| Conditions | Yield |
|---|---|
|
With
diisobutylaluminium hydride;
In
tetrahydrofuran;
at 50 ℃;
for 4h;
|
88% |
|
dicyclohexylphosphine oxide;
With
diisobutylaluminium hydride;
In
tetrahydrofuran; toluene;
at 20 ℃;
Inert atmosphere;
With
sodium hydroxide;
In
tetrahydrofuran; tert-butyl methyl ether; water; toluene;
at 5 ℃;
|
85% |
|
With
pinacolboronic acid;
In
acetonitrile;
at 20 ℃;
for 20h;
Inert atmosphere;
Glovebox;
Sealed tube;
Schlenk technique;
|
-
-
16523-54-9
chlorodicyclohexylphosphane
-
-
829-84-5
dicyclohexylphosphane
| Conditions | Yield |
|---|---|
|
With
lithium aluminium tetrahydride;
|
|
|
With
diisobutylaluminium hydride;
In
toluene;
at -78 - 23 ℃;
Inert atmosphere;
|
|
|
chlorodicyclohexylphosphane;
In
diethyl ether;
|
|
|
chlorodicyclohexylphosphane;
With
sodium;
In
toluene;
at 100 - 105 ℃;
Inert atmosphere;
With
tert-butyl alcohol;
In
toluene;
at 100 - 105 ℃;
Inert atmosphere;
|
829-84-5 Upstream products
-
15873-72-0
dicyclohexylphosphinoyl chloride
-
3676-98-0
tetracyclohexyl-diphosphane-P,P'-disulfide
-
931-51-1
cyclohexylmagnesiumchloride
-
19966-81-5
lithium dicyclohexylphosphide
829-84-5 Downstream products
-
832-39-3
dicyclohexylphosphinic acid
-
93189-63-0
Dicyclohexyl-ethoxycarbonylmethyl-phosphin
-
23743-26-2
1,2-bis-(dicyclohexylphosphino)ethane
-
52054-27-0
1-cyclohexyl-phospholane
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Cytidine 5'-monophosphate disodium salt
CAS:6757-06-8
-
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-
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CAS:54932-72-8

