829-84-5

  • Product Name:Dicyclohexylphosphine
  • Molecular Formula:C12H23P
  • Purity:99%
  • Molecular Weight:198.288
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Product Details;

CasNo: 829-84-5

Molecular Formula: C12H23P

Appearance: Colorless Liquid

factory and supplier 829-84-5 Dicyclohexylphosphine in stock

  • Molecular Formula:C12H23P
  • Molecular Weight:198.288
  • Appearance/Colour:Colorless Liquid 
  • Vapor Pressure:0.00373mmHg at 25°C 
  • Melting Point:2°C 
  • Refractive Index:n 20/D 1.516  
  • Boiling Point:289.8 °C at 760 mmHg 
  • Flash Point:129.1 °C 
  • PSA:13.59000 
  • Density:0.98 g/cm3 
  • LogP:4.33030 

DICYCLOHEXYLPHOSPHINE(Cas 829-84-5) Usage

General Description

Dicyclohexylphosphine is a chemical compound with the molecular formula C12H23P. It is a white solid at room temperature and is commonly used as a ligand in organometallic chemistry. Dicyclohexylphosphine is a strong donor of electron density, and its bulky nature allows it to stabilize metal centers in catalytic reactions. It is also often used in the synthesis of various organometallic complexes and as a reducing agent in organic synthesis. Additionally, dicyclohexylphosphine has been studied for its potential use in pharmaceutical and medicinal applications, showing promise as a versatile building block in the preparation of new drugs. Overall, dicyclohexylphosphine plays a crucial role in the field of organometallic chemistry and has a wide range of applications in both academic research and industrial processes.

InChI:InChI=1/C12H23P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h11-13H,1-10H2

829-84-5 Relevant articles

Copper-catalyzed C–P cross-coupling of secondary phosphines with (hetero)aromatic bromide

Li, Chun-Jing,Lü, Jing,Zhang, Zhi-Xun,Zhou, Kun,Li, Yan,Qi, Guang-Hui

, p. 4547 - 4562 (2018/04/20)

A novel and convenient approach to the s...

Rapid Metal-Free Formation of Free Phosphines from Phosphine Oxides

Provis-Evans, Cei B.,Emanuelsson, Emma A. C.,Webster, Ruth L.

supporting information, p. 3999 - 4004 (2018/09/21)

A rapid method for the reduction of seco...

Photo-initiator 2,4,6-trimethylbenzoyldicyclohexyloxyphosphine and preparation method and application thereof

-

Paragraph 0020; 0021, (2016/10/20)

The invention relates to a preparation m...

Phosphonium bis(glycolates) and phosphinoglycolates: Synthesis, solvolysis, oxidation to (thio)phosphinoylglycolates and use as ligands in Ni-catalyzed ethylene oligomerization

Peulecke, Normen,Kindermann, Markus K.,K?ckerling, Martin,Heinicke, Joachim

body text, p. 61 - 69 (2012/08/27)

Secondary phosphines, glyoxylic acid hyd...

829-84-5 Process route

dicyclohexylphosphine oxide
14717-29-4

dicyclohexylphosphine oxide

dicyclohexylphosphane
829-84-5

dicyclohexylphosphane

Conditions
Conditions Yield
With diisobutylaluminium hydride; In tetrahydrofuran; at 50 ℃; for 4h;
88%
dicyclohexylphosphine oxide; With diisobutylaluminium hydride; In tetrahydrofuran; toluene; at 20 ℃; Inert atmosphere;
With sodium hydroxide; In tetrahydrofuran; tert-butyl methyl ether; water; toluene; at 5 ℃;
85%
With pinacolboronic acid; In acetonitrile; at 20 ℃; for 20h; Inert atmosphere; Glovebox; Sealed tube; Schlenk technique;
chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

dicyclohexylphosphane
829-84-5

dicyclohexylphosphane

Conditions
Conditions Yield
With lithium aluminium tetrahydride;
With diisobutylaluminium hydride; In toluene; at -78 - 23 ℃; Inert atmosphere;
chlorodicyclohexylphosphane;
In diethyl ether;
chlorodicyclohexylphosphane; With sodium; In toluene; at 100 - 105 ℃; Inert atmosphere;
With tert-butyl alcohol; In toluene; at 100 - 105 ℃; Inert atmosphere;

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