577-19-5
- Product Name：1-Bromo-2-nitrobenzene
- Molecular Formula：C6H4BrNO2
- Purity：99%
- Molecular Weight：202.007
Product Details;
CasNo： 577-19-5
Molecular Formula： C6H4BrNO2
Appearance： white to light yellow crystal powder
factory and supplier 577-19-5 1-Bromo-2-nitrobenzene in stock
- Molecular Formula:C6H4BrNO2
- Molecular Weight:202.007
- Appearance/Colour:white to light yellow crystal powder
- Vapor Pressure:0.0192mmHg at 25°C
- Melting Point:40-42 °C(lit.)
- Refractive Index:1.605
- Boiling Point:261 °C at 760 mmHg
- Flash Point:87.8 °C
- PSA：45.82000
- Density:1.719 g/cm3
- LogP:2.88050
1-Bromo-2-nitrobenzene(Cas 577-19-5) Usage
|
Purification Methods |
Crystallise it twice from pet ether, using charcoal before the first crystallisation. [Beilstein 5 III 618, 5 IV 728.] |
|
General Description |
1-Bromo-2-nitrobenzene undergoes palladium[0]-mediated Ullmann cross-coupling reaction with a range of β-halo-enals, -enones or -esters to afford the corresponding β-aryl derivatives. Palladium[0]-mediated Ullmann cross-coupling reaction of 1-bromo-2-nitrobenzene with β-bromo-α,β-unsaturated aldehydes is reported. |
InChI:InChI=1/C6H4BrNO2/c7-5-3-1-2-4-6(5)8(9)10/h1-4H
577-19-5 Relevant articles
Nitration of deactivated aromatic compounds via mechanochemical reaction
Wu, Jian-Wei,Zhang, Pu,Guo, Zhi-Xin
supporting information, (2021/05/05)
A variety of deactivated arenes were nit...
Nitration of aromatics with dinitrogen pentoxide in a liquefied 1,1,1,2-tetrafluoroethane medium
Fauziev, Ruslan V.,Kharchenko, Alexandr K.,Kuchurov, Ilya V.,Zharkov, Mikhail N.,Zlotin, Sergei G.
, p. 25841 - 25847 (2021/08/09)
Regardless of the sustainable developmen...
Low-temperature and highly efficient liquid-phase catalytic nitration of chlorobenzene with NO2: Remarkably improving the para-selectivity in O2-Ac2O-Hβ composite system
Deng, Renjie,Liu, Pingle,Luo, He'an,Ni, Wenjin,You, Kuiyi,Zhao, Fangfang
, (2020/02/26)
In this work, we developed a low-tempera...
Oxidative bromination of non-activated aromatic compounds with AlBr3/KNO3 mixture
Rahu, Ida,J?rv, Jaak
, p. 1219 - 1227 (2019/11/13)
Bromination of non-activated aromatic co...
577-19-5 Process route
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C14H10Br2F3IO4S
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577-19-5
2-nitrophenyl bromide
| Conditions | Yield |
|---|---|
|
With
sodium nitrite;
In
1,2-dichloro-ethane;
at 20 - 80 ℃;
Schlenk technique;
|
85% |
-
-
5570-19-4
2-nitrophenylboronic acid
-
-
577-19-5
2-nitrophenyl bromide
| Conditions | Yield |
|---|---|
|
With
sodium nitrite;
In
acetonitrile;
at 80 ℃;
for 20h;
Sealed tube;
|
80% |
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