429-42-5
- Product Name：Tetrabutylammonium tetrafluoroborate
- Molecular Formula：C16H36BF4N
- Purity：99%
- Molecular Weight：329.273
Product Details;
CasNo： 429-42-5
Molecular Formula： C16H36BF4N
Appearance： white crystalline powder
factory and manufacture 429-42-5 Tetrabutylammonium tetrafluoroborate lonic liquid
- Molecular Formula:C16H36BF4N
- Molecular Weight:329.273
- Appearance/Colour:white crystalline powder
- Melting Point:155-161 °C
- Flash Point:>93℃
- PSA：0.00000
- LogP:6.30360
Tetrabutylammonium tetrafluoroborate(Cas 429-42-5) Usage
|
Purification Methods |
Recrystallise it from H2O, aqueous EtOH or from EtOAc by cooling in Dry-ice. Also recrystallise it from ethyl acetate/pentane or dry acetonitrile. Dry it at 80o under vacuum. [Detty & Jones J Am Chem Soc 109 5666 1987, Hartley & Faulkner J Am Chem Soc 107 3436 1985.] The acetate has m 118±2o (from BuCl), the bromide has m 118o (from EtOAc) and the nitrate has m 120o (from *C6H6). [Witschonka & Kraus J Am Chem Soc 69 2472 1947, Wheeler & Sandstedt J Am Chem Soc 77 2024 1955, Beilstein 4 IV 558.] |
|
General Description |
Tetrabutylammonium tetrafluoroborate (TBATFB) is a phase transfer catalyst. It can be synthesized by the reaction between 30% aqueous solution of tetrafluoroboric acid and 40% aqueous solution of tetrabutylamonium hydroxide. Tetrabutylammonium tetrafluoroborate acts as an electrolyte and inhibits the self-assembly of alkylthiosulfate on gold. |
InChI:InChI=1/C16H36N.BF4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;/q+1;-1
429-42-5 Relevant articles
Electrochemical studies of the nickel catecholate complexes for detection of sulphur dioxide gas
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, p. 4314 - 4318 (2010)
Nickel catecholate complexes, bis(diphen...
External oxidant-free cross-coupling: Electrochemically induced aromatic C-H phosphonation of azoles with dialkyl-: H -phosphonates under silver catalysis
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, p. 190 - 196 (2018)
A convenient external oxidant-free metho...
Controlling Metal-to-Oxygen Ratios via M=O Bond Cleavage in Polyoxovanadate Alkoxide Clusters
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, p. 10462 - 10471 (2019)
In this manuscript, we further investiga...
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, p. 25287 - 25294 (2015)
In transportation vehicles, a large port...
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Transition-metal Complexes of Crown Ether Benzodithiolenes. Part 2. The Effects of Alkali-metal Cation Binding
Lowe, Nigel D.,Garner, C. David
, p. 3333 - 3340 (1993)
The binding of Li(+), Na(+) and K(+) cat...
Stereoelectronic and Resonance Effects on the Rate of Ring Opening of N-Cyclopropyl-Based Single Electron Transfer Probes
Grimm, Michelle L.,Suleman, N. Kamrudin,Hancock, Amber N.,Spencer, Jared N.,Dudding, Travis,Rowshanpour, Rozhin,Castagnoli, Neal,Tanko, James M.
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supporting information, (2020/03/13)
Equilibrium constants for the associatio...
429-42-5 Process route
-
-
1375484-96-0
[Bu4N][C4H9BF3]
-
-
542-69-8
1-iodo-butane
-
-
429-42-5
tetrabutylammonium tetrafluoroborate
-
-
106-97-8,9003-29-6,9021-92-5
n-butane
| Conditions | Yield |
|---|---|
|
With
Iodine monochloride;
In
dichloromethane;
at 20 ℃;
for 1h;
|
-
-
1643-19-2
tetrabutylammomium bromide
-
-
429-42-5
tetrabutylammonium tetrafluoroborate
| Conditions | Yield |
|---|---|
|
With
potassium tetrafluoroborate;
In
dichloromethane; water;
at 20 ℃;
for 24h;
|
96% |
|
With
potassium tetrafluoroborate;
In
dichloromethane; water;
at 20 ℃;
for 24h;
|
96% |
|
With
potassium tetrafluoroborate;
In
dichloromethane; water;
at 20 ℃;
for 24h;
|
96% |
|
With
trimethyl phosphite; tetrafluoroboric acid;
at 0 - 60 ℃;
for 15h;
Inert atmosphere;
neat (no solvent);
|
90% |
|
With
potassium tetrafluoroborate;
In
water;
|
|
|
With
sodium tetrafluoroborate;
In
water;
|
429-42-5 Upstream products
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102-82-9
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2752-95-6
butyl diphenyl phosphate
-
46438-39-5
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71-43-2
benzene
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