564483-19-8
- Product Name：2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl
- Molecular Formula：C29H45P
- Purity：99%
- Molecular Weight：424.65
Product Details;
CasNo： 564483-19-8
Molecular Formula： C29H45P
factory and supplier 564483-19-8 2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl in stock
- Molecular Formula:C29H45P
- Molecular Weight:424.65
- Melting Point:148-151 °C(lit.)
- Boiling Point:493.479ºC at 760 mmHg
- Flash Point:267.742ºC
- PSA：13.59000
- LogP:9.42800
564483-19-8 Relevant articles
Synthesis of di-tert-butylphenol [...] biphenyl compounds (by machine translation)
-
Paragraph 0013, (2019/03/06)
The invention discloses a method for syn...
A preparation method of compound phosphine benzene apperception (by machine translation)
-
Paragraph 0078; 0079; 0080; 0081, (2016/11/14)
The invention relates to a method for pr...
Expanding Pd-catalyzed C-N bond-forming processes: The first amidation of aryl sulfonates, aqueous amination, and complementarity with Cu-catalyzed reactions
Huang, Xiaohua,Anderson, Kevin W.,Zim, Danilo,Jiang, Lei,Klapars, Artis,Buchwald, Stephen L.
, p. 6653 - 6655 (2007/10/03)
The first general method for the Pd-cata...
564483-19-8 Process route
-
-
13716-10-4
di(tert-butyl)chlorophosphine
-
-
694-80-4
2-bromo-1-chlorobenzene
-
-
21524-34-5
2,4,6-triisopropyl-1-bromobenzene
-
-
564483-19-8
tert-butyl XPhos
| Conditions | Yield |
|---|---|
|
2-bromo-1-chlorobenzene; 2,4,6-triisopropyl-1-bromobenzene;
With
magnesium;
In
tetrahydrofuran;
for 2h;
Inert atmosphere;
Reflux;
di(tert-butyl)chlorophosphine;
With
tetrakis(triphenylphosphine) palladium(0);
In
tetrahydrofuran;
at 20 ℃;
for 5.5h;
Reagent/catalyst;
Reflux;
Inert atmosphere;
|
94% |
|
2,4,6-triisopropyl-1-bromobenzene;
With
magnesium; ethylene dibromide;
In
tetrahydrofuran;
at 65 ℃;
for 1h;
2-bromo-1-chlorobenzene;
In
tetrahydrofuran;
at 65 ℃;
for 1h;
di(tert-butyl)chlorophosphine;
With
copper(l) chloride;
In
tetrahydrofuran;
at 20 ℃;
for 20h;
|
32% |
-
-
819-19-2
di-tert-butylphosphine
-
-
154549-38-9
2,4,6-triisopropylphenylboronic acid
-
-
583-53-9
2,3-dibromobenzene
-
-
564483-19-8
tert-butyl XPhos
| Conditions | Yield |
|---|---|
|
di-tert-butylphosphine; 2,3-dibromobenzene;
With
bis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(0); sodium carbonate;
In
toluene;
at 80 ℃;
for 8h;
Inert atmosphere;
2,4,6-triisopropylphenylboronic acid;
In
toluene;
at 100 ℃;
for 12h;
Inert atmosphere;
|
86% |
564483-19-8 Upstream products
-
13716-10-4
di(tert-butyl)chlorophosphine
-
694-80-4
2-bromo-1-chlorobenzene
-
21524-34-5
2,4,6-triisopropyl-1-bromobenzene
-
819-19-2
di-tert-butylphosphine
564483-19-8 Downstream products
-
890315-26-1
tert-butyl 2-(benzamido)-4-(3-methoxyphenoxy)benzoate
-
890316-67-3
tert-butyl 2-(benzamido)-4-(3-nitrophenoxy)benzoate
-
890315-15-8
tert-butyl 2-(benzamido)-4-(3,5-difluorophenoxy)benzoate
-
890316-64-0
tert-butyl 2-(benzamido)-4-(4-methylphenoxy)benzoate
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