369-36-8

  • Product Name:2-Fluoro-5-nitroaniline
  • Molecular Formula:C6H5FN2O2
  • Purity:99%
  • Molecular Weight:156.116
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Product Details;

CasNo: 369-36-8

Molecular Formula: C6H5FN2O2

Appearance: ochre-yellow to light brown crystalline powder

factory and supplier 369-36-8 2-Fluoro-5-nitroaniline in stock

  • Molecular Formula:C6H5FN2O2
  • Molecular Weight:156.116
  • Appearance/Colour:ochre-yellow to light brown crystalline powder 
  • Melting Point:97-100 °C(lit.) 
  • Boiling Point:295.5 °C at 760 mmHg 
  • PKA:1.13±0.10(Predicted) 
  • Flash Point:91.1 °C 
  • PSA:71.84000 
  • Density:1.448 g/cm3 
  • LogP:2.42050 

2-Fluoro-5-nitroaniline(Cas 369-36-8) Usage

Synthesis Reference(s)

Tetrahedron Letters, 31, p. 6141, 1990 DOI: 10.1016/S0040-4039(00)97008-4

InChI:InChI=1/C6H5FN2O2/c7-5-2-1-4(9(10)11)3-6(5)8/h1-3H,8H2

369-36-8 Relevant articles

A Metal-Free Direct Arene C?H Amination

Wang, Tao,Hoffmann, Marvin,Dreuw, Andreas,Hasagi?, Edina,Hu, Chao,Stein, Philipp M.,Witzel, Sina,Shi, Hongwei,Yang, Yangyang,Rudolph, Matthias,Stuck, Fabian,Rominger, Frank,Kerscher, Marion,Comba, Peter,Hashmi, A. Stephen K.

supporting information, p. 2783 - 2795 (2021/04/05)

The synthesis of aryl amines via the for...

Selective partial hydrogenation of dinitrobenzenes to nitroanilines catalyzed by Ru/C

Hou, Jie,Ma, Yonghuan,Li, Yuhan,Guo, Fang,Lu, Lianhai

scheme or table, p. 974 - 975 (2009/04/06)

Ru/C was found to be a highly effective ...

Effect of the electronic structure of the radical anions of 4-substituted 1,2-and 1,3-dinitrobenzenes on the regioselectivity of reduction of the nitro groups

Orlov,Begunov,Demidova,Rusakov

, p. 76 - 81 (2007/10/03)

Theoretical and experimental regularitie...

Catalytic reduction of dinitrobenzenes using a noble metal catalyst and iron or iron salts

-

, (2008/06/13)

There is provided an improved process fo...

369-36-8 Process route

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Conditions
Conditions Yield
With hydrogen; iron; acetic acid; palladium dichloride; In ethanol; at 20 - 25 ℃; for 1.25h; under 258.6 - 2327.2 Torr; Product distribution; other noble metal catalysts, variation of condition; other polynitro compounds;
87%
With hydrogen; iron; acetic acid; palladium dichloride; In ethanol; at 20 - 25 ℃; for 1.25h; under 258.6 - 2327.2 Torr; Yields of byproduct given;
87%
With hydrogen; In ethanol; acetic acid;
17.6%
With hydrogenchloride; ethanol; tin(ll) chloride;
With titanium(III) chloride; In methanol; water; Title compound not separated from byproducts;
25.97 % Chromat.
25.75 % Chromat.
With ruthenium on carbon; hydrogen; at 50 ℃; under 7500.75 Torr;
2,4-Dinitrofluorobenzene
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6-fluoro-3-nitroaniline
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6-fluoro-3-nitroaniline

Conditions
Conditions Yield
With hydrogen; palladium; In ethanol; water; acetic acid;
17.6%
With ethanol; tin(ll) chloride;
With hydrogen; iron; palladium; In ethanol; water; acetic acid;
With hydrogen; iron; acetic acid; In ethanol; water;
With hydrogen; iron; In ethanol; water; acetic acid;

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