822-85-5
- Product Name：2-broMocyclohexan-1-one
- Molecular Formula：C6H9BrO
- Purity：99%
- Molecular Weight：177.041
Product Details;
CasNo： 822-85-5
Molecular Formula： C6H9BrO
factory and supplier 822-85-5 2-broMocyclohexan-1-one in stock
- Molecular Formula:C6H9BrO
- Molecular Weight:177.041
- Vapor Pressure:0.191mmHg at 25°C
- Refractive Index:1.516
- Boiling Point:210.544 °C at 760 mmHg
- Flash Point:83.69 °C
- PSA：17.07000
- Density:1.509 g/cm3
- LogP:1.89300
2-BROMO-CYCLOHEXANONE(Cas 822-85-5) Usage
|
Synthesis Reference(s) |
Journal of the American Chemical Society, 90, p. 6218, 1968 DOI: 10.1021/ja01024a051Tetrahedron Letters, 20, p. 3653, 1979 DOI: 10.1016/S0040-4039(01)95488-7 |
InChI:InChI=1/C6H9BrO/c7-5-3-1-2-4-6(5)8/h5H,1-4H2
822-85-5 Relevant articles
Quinoxaline compound, preparation method and application of quinoxaline compound in medicine
-
Paragraph 0203-0206, (2021/07/24)
The invention provides a quinoxaline com...
Diastereoselective Additions of Allylmagnesium Reagents to α-Substituted Ketones When Stereochemical Models Cannot Be Used
Bartolo, Nicole D.,Demkiw, Krystyna M.,Valentín, Elizabeth M.,Hu, Chunhua T.,Arabi, Alya A.,Woerpel
, p. 7203 - 7217 (2021/05/29)
The stereoselectivities of reactions of ...
Copper-Mediated Dichotomic Borylation of Alkyne Carbonates: Stereoselective Access to (E)-1,2-Diborylated 1,3-Dienes versus Traceless Monoborylation Affording α-Hydroxyallenes
Guo, Kun,Kleij, Arjan W.
supporting information, p. 4901 - 4906 (2021/01/21)
A mild copper-mediated protocol has been...
Flexible on-site halogenation paired with hydrogenation using halide electrolysis
Shang, Xiao,Liu, Xuan,Sun, Yujie
supporting information, p. 2037 - 2043 (2021/03/26)
Direct electrochemical halogenation has ...
822-85-5 Process route
-
-
110-83-8
cyclohexene
-
-
1056477-06-5,822-85-5
2-bromocyclohexanone
-
-
5401-62-7
1,2-dibromocyclohexane
-
-
24796-87-0,5537-67-7
2-bromo-cyclohexanol
| Conditions | Yield |
|---|---|
|
With
sodium bromate; sulfuric acid; sodium bromide;
In
1,4-dioxane; water;
at 20 ℃;
for 8h;
|
46% 7% 6% |
|
With
hydrogen bromide; dihydrogen peroxide; potassium bromide;
ammonium metavanadate;
In
chloroform;
at 20 ℃;
for 24h;
|
46 % Spectr. 24 % Spectr. 20 % Spectr. |
|
With
ammonium metavanadate; perchloric acid; tetrabutylammomium bromide; dihydrogen peroxide;
In
chloroform; water;
at 20 ℃;
for 0.5h;
|
46 %Chromat. 20 %Chromat. 24 %Chromat. |
-
-
110-83-8
cyclohexene
-
-
1056477-06-5,822-85-5
2-bromocyclohexanone
-
-
5401-62-7
1,2-dibromocyclohexane
| Conditions | Yield |
|---|---|
|
With
sodium bromite;
In
water; acetic acid;
for 5h;
Yields of byproduct given;
Ambient temperature;
|
87% |
|
With
sodium bromite;
In
water; acetic acid;
for 5h;
Yield given;
Ambient temperature;
|
87% |
822-85-5 Upstream products
-
108-94-1
cyclohexanone
-
822-87-7
2-Chlorocyclohexanone
-
1424-22-2
1-cyclohexenyl acetate
-
108-93-0
cyclohexanol
822-85-5 Downstream products
-
4433-49-2
4,5,6,7-tetrahydrobenzo[d]thiazole
-
4513-77-3
2-cyanocyclohexanone
-
52190-35-9
2-(methylthio)cyclohexanone
-
17472-04-7
2-acetoxycyclohexanone
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