13080-90-5
- Product Name:5-Norbornene-2-ol
- Molecular Formula:C7H10O
- Purity:99%
- Molecular Weight:110.156
Product Details;
CasNo: 13080-90-5
Molecular Formula: C7H10O
factory and supplier 13080-90-5 5-Norbornene-2-ol in stock
- Molecular Formula:C7H10O
- Molecular Weight:110.156
- Vapor Pressure:0.218mmHg at 25°C
- Melting Point:104-106 °C(lit.)
- Refractive Index:1.574
- Boiling Point:183.7 °C at 760 mmHg
- PKA:14.85±0.20(Predicted)
- Flash Point:62 °C
- PSA:20.23000
- Density:1.153 g/cm3
- LogP:0.94330
5-NORBORNENE-2-OL(Cas 13080-90-5) Usage
InChI:InChI=1/C7H10O/c8-7-4-5-1-2-6(7)3-5/h1-2,5-8H,3-4H2
13080-90-5 Relevant articles
Stereoselective [4+2]-Cycloaddition with Chiral Alkenylboranes
Brown, M. Kevin,Houk, K. N.,Ni, Dongshun,Witherspoon, Brittany P.,Zhang, Hong,Zhou, Chen
supporting information, p. 11432 - 11439 (2020/05/18)
A method for the stereoselective [4+2]-c...
Alkylhalovinylboranes: a new class of Diels-Alder dienophiles
Pisano, Pablo L.,Pellegrinet, Silvina C.
, p. 33864 - 33871 (2018/10/20)
The Diels-Alder reactions of alkylhalovi...
α-Hydroxyacids accelerate the Diels-Alder reaction of dibutyl vinylboronate with cyclopentadiene: Experimental results and mechanistic insights
Grimblat,Sarotti,Pisano,Pellegrinet
, p. 1966 - 1969 (2016/03/22)
We have found that α-hydroxyacids accele...
Diels-Alder reactions of pinacol alkenylboronates: An experimental and theoretical study
Vallejos, Margarita M.,Grimblat, Nicolas,Pellegrinet, Silvina C.
, p. 36385 - 36400 (2014/12/09)
We have studied the Diels-Alder reaction...
13080-90-5 Process route
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-
694-98-4
norborn-5-en-2-one
-
-
694-97-3,2890-98-4,13080-90-5,69769-90-0,71030-14-3,71030-15-4,87392-59-4,106928-44-3,16620-80-7
(1S,2S,4S)-bicyclo[2.2.1]hept-5-en-2-ol
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-
106928-44-3
(1R,2R,4R)-endo-bicyclo[2.2.1]hept-5-en-2-ol
| Conditions | Yield |
|---|---|
|
With
D-glucose 6-phosphate; TEA buffer with NAD+;
In
water;
for 36h;
Title compound not separated from byproducts;
Ambient temperature;
Bacillus stearothermophilus alcohol dehydrogenase;
|
45% |
-
-
694-98-4
norborn-5-en-2-one
-
-
694-97-3,2890-98-4,13080-90-5,69769-90-0,71030-14-3,71030-15-4,87392-59-4,106928-44-3,16620-80-7
(1S,2S,4S)-bicyclo[2.2.1]hept-5-en-2-ol
| Conditions | Yield |
|---|---|
|
Multi-step reaction with 4 steps
1: NaBH4 / methanol / -10 °C
2: DMAP, pyridine / Ambient temperature
4: 88 percent / LiAlH4 / diethyl ether / 1.) -5 deg C, 2 h, 2.) 0 deg C, 1 h
With
pyridine; dmap; sodium tetrahydroborate; lithium aluminium tetrahydride;
In
methanol; diethyl ether;
|
13080-90-5 Upstream products
-
108-05-4
vinyl acetate
-
542-92-7
cyclopenta-1,3-diene
-
694-97-3
endo-5-norbornen-2-ol
-
16620-79-4
(-)-<1S,4S>bicyclo<2.2.1>heptene-5 one-2
13080-90-5 Downstream products
-
135560-55-3
5-endo-Bromo-6-exo-(phenylselenyl)bicyclo<2.2.1>heptan-2-exo-ol
-
135560-56-4
6-endo-Bromo-5-exo-(phenylselenyl)bicyclo<2.2.1>heptan-2-exo-ol
-
497-38-1
Norbornan-2-on
-
497-36-9
Norborneol
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