171058-17-6
- Product Name：1-Hexyl-3-MethylImidazolium Chloride
- Molecular Formula：C10H19ClN2
- Purity：99%
- Molecular Weight：202.727
Product Details;
CasNo： 171058-17-6
Molecular Formula： C10H19ClN2
Appearance： Clear yellow-orange liquid
factory and manufacture 171058-17-6 1-Hexyl-3-MethylImidazolium Chloride lonic liquid
- Molecular Formula:C10H19ClN2
- Molecular Weight:202.727
- Appearance/Colour:Clear yellow-orange liquid
- Melting Point:-85 °C
- Refractive Index:1.514-1.518
- PSA：8.81000
- Density:1.0337 g/cm3
- LogP:-1.10310
1-Hexyl-3-methylimidazolium chloride(Cas 171058-17-6) Usage
|
Conductivity |
0.08 mS/cm |
|
General Description |
1-Hexyl-3-methylimidazolium chloride ([C6mim][Cl]) is an ionic liquid with dynamic viscosity, density, and refractive index properties that have been measured across a temperature range of 298.15–343.15 K. Its binary mixtures with water exhibit temperature-dependent behavior, with excess molar volumes and viscosity deviations fitting the Redlich-Kister equation. Additionally, its thermal diffusivity and sound speed have been studied, showing that the anion type significantly influences these properties, while the cation size has minimal impact. The standard molar enthalpy of solution for [C6mim][Cl] in water has been determined, with Pitzer's parameters providing insights into its thermodynamic behavior. |
InChI:InChI=1/C10H19N2/c1-3-4-5-6-7-12-9-8-11(2)10-12/h8-10H,3-7H2,1-2H3/q+1
171058-17-6 Relevant articles
Dynamic viscosities of a series of 1-alkyl-3-methylimidazolium chloride ionic liquids and their binary mixtures with water at several temperatures
Gomez, Elena,Gonzalez, Begona,Dominguez, Angeles,Tojo, Emilia,Tojo, Jose
, p. 696 - 701 (2006)
Dynamic viscosities, densities, and refr...
An efficient, eco-friendly, one-pot protocol for the synthesis of 2-oxazolines promoted by ionic liquid/indium chloride
Kamakshi,Reddy, Boreddy S.R.
, p. 463 - 467 (2006)
2-Oxazolines have been synthesized using...
Adsorption of arsenic from aqueous solution using a zero-valent iron material modified by the ionic liquid [Hmim]SbF6
Wu, Fenghui,Zhao, Chenyang,Qu, Guangfei,Yan, Zhoupeng,Zeng, Yingda,Chen, Bangjin,Hu, Yinghui,Ji, Wei,Li, Yingli,Tang, Huimin
, p. 6577 - 6585 (2021)
The environmental and health impacts cau...
Determination of thermal diffusivities, thermal conductivities, and sound speeds of room-temperature ionic liquids by the transient grating technique
Frez, Clifford,Diebold, Gerald J.,Tran, Chieu D.,Yu, Shaofang
, p. 1250 - 1255 (2006)
We report measurements of thermal diffus...
Solution enthalpies of ionic liquid 1-hexyl-3-methylimidazolium chloride
Fang, Da-Wei,Sun, Ying-Chun,Wang, Zhen-Wei
, p. 259 - 261 (2008)
The molar enthalpies of solution of ioni...
Measurement of high-pressure densities and atmospheric viscosities of ionic liquids: 1-hexyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide and 1-Hexyl-3-methylimidazolium chloride
Iguchi, Masayuki,Hiraga, Yuya,Sato, Yoshiyuki,Aida, Taku Michael,Watanabe, Masaru,Smith Jr., Richard L.
, p. 709 - 717 (2014)
Atmospheric densities and viscosities of...
Properties and catalytic activity of magnetic and acidic ionic liquids: Experimental and molecular simulation
Zhou, Cunshan,Yu, Xiaojie,Ma, Haile,Huang, Xingyi,Zhang, Henan,Jin, Jian
, p. 300 - 307 (2014)
The exploitation of dual functional magn...
Photophysical properties of lanthanide (Eu 3+, Tb 3+) hybrid soft gels of double functional linker of ionic liquid-modified silane
Li, Qiu-Ping,Yan, Bing
, p. 22 - 28 (2014)
Four kinds of luminescent hybrid soft ge...
Phase diagram data for several salt + salt aqueous biphasic systems at 298.15 K
Deng, Yuefeng,Chen, Ji,Zhang, Dongli
, p. 1332 - 1335 (2007)
Phase diagrams corresponding to aqueous ...
Hydrogels dispersed by doped rare earth fluoride nanocrystals: Ionic liquid dispersion and down/up-conversion luminescence
Yan, Zhi-Yuan,Jia, Li-Ping,Yan, Bing
, p. 732 - 736 (2014)
Two typical kinds of rare earth fluoride...
Infrared spectroscopic study of absorption and separation of CO using copper(i)-containing ionic liquids
Repper, Stephen E.,Haynes, Anthony,Ditzel, Evert J.,Sunley, Glenn J.
, p. 2821 - 2828 (2017)
Absorption of carbon monoxide by copper(...
Dicyanoaurate(I) salts with 1-alkyl-3-methylimidazolium: Luminescent properties and room-temperature liquid forming
Yoshida, Yukihiro,Fujii, Junichi,Saito, Gunzi,Hiramatsu, Takaaki,Sato, Naoki
, p. 724 - 727 (2006)
Room-temperature ionic liquids containin...
Liquid-liquid interfacial tension of equilibrated mixtures of ionic liquids and hydrocarbons
Rodriguez, Hector,Arce, Alberto,Soto, Ana
, p. 1519 - 1524 (2012)
Ionic liquids are possible alternative s...
Synthesis, structure, and physico-optical properties of manganate(II)-based ionic liquids
Pitula, Slawomir,Mudring, Anja-Verena
, p. 3355 - 3365 (2010)
Several ionic liquids (ILs) based on com...
Enhanced antimicrobial activities of 1-alkyl-3-methyl imidazolium ionic liquids based on silver or copper containing anions
Gilmore, Brendan F.,Andrews, Gavin P.,Borberly, Gabor,Earle, Martyn J.,Gilea, Manuela A.,Gorman, Sean P.,Lowry, Andrew F.,McLaughlin, Martin,Seddon, Kenneth R.
, p. 873 - 876 (2013)
We have developed a series of 1-alkyl-3-...
Solvent-free sonochemical preparation of ionic liquids.
Namboodiri, Vasudevan V,Varma, Rajender S
, p. 3161 - 3163 (2002)
[reaction: see text] An ultrasound-assis...
Crystalline and liquid crystalline organic-inorganic hybrid salts with cation-sensitized hexanuclear molybdenum cluster complex anion luminescence
Baecker, Joanna,Mihm, Svenja,Mallick, Bert,Yang, Mei,Meyer, Gerd,Mudring, Anja-Verena
, p. 4089 - 4095 (2011)
The salts [Cnmim]2[Mo6Cl14] (mim = methy...
Antibiofilm activities of 1-alkyl-3-methylimidazolium chloride ionic liquids
Carson, Louise,Chau, Peter K. W.,Earle, Martyn J.,Gilea, Manuela A.,Gilmore, Brendan F.,Gorman, Sean P.,McCann, Maureen T.,Seddon, Kenneth R.
, p. 492 - 497 (2009)
Microbial biofilms are ubiquitous in nat...
Densities, excess molar and partial molar volumes for water + 1-butyl- or, 1-hexyl- or, 1-octyl-3-methylimidazolium halide room temperature ionic liquids at T = (298.15 and 308.15) K
Sastry, Nandhibatla V.,Vaghela, Nilesh M.,Macwan, Pradip M.
, p. 12 - 18 (2013)
Experimental densities for seven mixture...
Densities and viscosities of binary mixtures of magnetic ionic liquids 1-alkyl-3-methylimidazolium tetrachloroferrate with ethyl acetate at temperatures (293.15 to 323.15) K
Li, Xiaohua,Zhou, Qing,Lu, Xingmei,Zhang, Suojiang
, p. 285 - 292 (2017)
The physicochemical properties of the bi...
Lonization state and ion migration mechanism of room temperature molten dialkylimidazolium fluorohydrogenates
Saito, Yuria,Hirai, Kenichi,Matsumoto, Kazuhiko,Hagiwara, Rika,Minamizaki, Yoshihiro
, p. 2942 - 2948 (2005)
The ionization state of room temperature...
An expeditious solvent-free route to ionic liquids using microwaves
Varma,Namboodiri
, p. 643 - 644 (2001)
A microwave-assisted preparation of a se...
Thermodynamic evaluation of imidazolium based ionic liquids with thiocyanate anion as effective solvent to thiophene extraction
Shekaari, Hemayat,Zafarani-Moattar, Mohammed Taghi,Niknam, Mehrdad
, p. 975 - 984 (2016)
In order to have deep insight on the mol...
Purification of imidazolium ionic liquids for spectroscopic applications
Nockemann, Peter,Binnemans, Koen,Driesen, Kris
, p. 131 - 136 (2005)
Ionic liquids are often contaminated by ...
Transition-metal- and phosphorus-free electrophilic trifluoromethylthiolation of indoles with sodium trifluoromethanesulfinates in ionic liquids
Wang, Fei,Lu, Guo-Ping,Lin, Yamei
supporting information, (2021/04/12)
An acid-promoted protocol has been devel...
The one-pot synthesis of butyl-1H-indol-3-alkylcarboxylic acid derivatives in ionic liquid as potent dual-acting agent for management of BPH
Chen, Kaixuan,Jiang, Zhenzhou,Liu, Shuwen,Xi, Baomin,Yang, Fubiao,Zeng, Li-Yan,Zeng, Yunong
, (2020/09/18)
Based on the SAR of both α1-AR antagonis...
Various metal organic frameworks combined with imidazolium, quinolinum and benzothiazolium ionic liquids for removal of three antibiotics from water
Yohannes, Alula,Li, Jing,Yao, Shun
, (2020/10/02)
In this research, imidazolium, quinolinu...
171058-17-6 Process route
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-
85100-78-3
1-hexyl-3-methyl-1-imidazolium bromide
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-
171058-17-6
1-hexyl-3-methylimidazol-1-ium chloride
| Conditions | Yield |
|---|---|
|
With
hydrogenchloride;
In
acetone;
at 40 ℃;
for 10h;
|
-
-
616-47-7
1-methyl-1H-imidazole
-
-
544-10-5
1-Chlorohexane
-
-
171058-17-6
1-hexyl-3-methylimidazol-1-ium chloride
| Conditions | Yield |
|---|---|
|
In
toluene;
at 112 - 113 ℃;
for 3h;
|
100% |
|
at 80 - 90 ℃;
Inert atmosphere;
|
96% |
|
for 0.5h;
ultrasonic irradiation;
|
89% |
|
for 0.0416667h;
Microwave irradiation;
neat (no solvent);
|
89% |
|
at 70 - 80 ℃;
|
87% |
|
at 70 - 100 ℃;
for 0.025h;
Microwave irradiation;
|
81% |
|
at 80 ℃;
for 48h;
|
80% |
|
at 60 ℃;
for 48h;
|
80% |
|
In
toluene;
at 48 ℃;
for 168000h;
|
76% |
|
|
|
|
|
|
|
Heating;
|
|
|
at 59.85 ℃;
|
|
|
for 48h;
Heating;
|
|
|
at 80 ℃;
for 70h;
|
|
|
at 20 - 90 ℃;
for 18h;
under 3878.71 Torr;
|
|
|
In
acetonitrile;
Inert atmosphere;
|
|
|
at 100 ℃;
Inert atmosphere;
|
|
|
at 90 ℃;
for 96h;
Autoclave;
|
|
|
In
tert-butyl methyl ether;
at 65 ℃;
|
|
|
In
acetonitrile;
at 39.99 ℃;
for 72h;
Inert atmosphere;
|
|
|
In
acetonitrile;
for 72h;
Reflux;
Inert atmosphere;
|
|
|
for 48h;
Inert atmosphere;
|
|
|
In
acetonitrile;
at 199.99 ℃;
|
|
|
at 100 ℃;
Inert atmosphere;
|
|
|
Thermodynamic data;
Heating;
|
|
|
at 80 ℃;
for 168h;
|
|
|
at 85 ℃;
for 36h;
Inert atmosphere;
|
|
|
In
acetonitrile;
|
|
|
at 80 ℃;
for 48h;
|
|
|
for 168h;
Inert atmosphere;
|
|
|
Reflux;
|
|
|
for 72h;
Reflux;
Inert atmosphere;
|
|
|
at 140 ℃;
for 2h;
|
|
|
In
ethyl acetate;
for 24h;
Reflux;
|
|
|
at 69.99 ℃;
for 48h;
|
|
|
at 70 ℃;
for 24h;
|
|
|
In
acetonitrile;
at 70 ℃;
for 6h;
|
|
|
at 70 ℃;
for 24h;
|
|
|
In
ethyl acetate;
for 24h;
Reflux;
|
171058-17-6 Upstream products
-
616-47-7
1-methyl-1H-imidazole
-
544-10-5
1-Chlorohexane
-
85100-78-3
1-hexyl-3-methyl-1-imidazolium bromide
171058-17-6 Downstream products
-
544-10-5
1-Chlorohexane
-
382150-50-7
1-hexyl-3-methylimidazolium bis-(trifluoromethanesulfonyl)amide
-
244193-50-8
1-hexyl-3-methylimidazolium tetrafluoroborate
-
1002753-68-5
1-n-hexyl-3-methylimidazolium 2-(phenylsulfanyl)-1,1,2,2-tetrafluoroethanesulfonate
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