461-97-2
- Product Name：3,5-Dimethylfluorobenzene
- Molecular Formula：C8H9F
- Purity：99%
- Molecular Weight：124.158
Product Details;
CasNo： 461-97-2
Molecular Formula： C8H9F
Appearance： clear colorless to slightly yellow liquid
factory and supplier 461-97-2 3,5-Dimethylfluorobenzene in stock
- Molecular Formula:C8H9F
- Molecular Weight:124.158
- Appearance/Colour:clear colorless to slightly yellow liquid
- Vapor Pressure:5.61mmHg at 25°C
- Refractive Index:1.475
- Boiling Point:145 ºC
- Flash Point:35 ºC
- PSA：0.00000
- Density:0.983g/cm3
- LogP:2.44250
5-FLUORO-M-XYLENE(Cas 461-97-2) Usage
InChI:InChI=1/C8H9F/c1-6-3-7(2)5-8(9)4-6/h3-5H,1-2H3
461-97-2 Relevant articles
Full continuous flow synthesis process of fluorine-containing aromatic hydrocarbon compounds
-
Paragraph 0123-0136, (2021/04/07)
The invention provides a full continuous...
Preparation method of 3,5-dimethylfluorobenzene
-
Paragraph 0041-0053, (2020/07/02)
The invention provides a preparation met...
Synthetic method for 1,5-bis(chloromethyl)-3-fluorobenzene
-
Paragraph 0007, (2017/02/17)
The invention discloses a synthetic meth...
FLUORINATION OF ARYL COMPOUNDS
-
Paragraph 00122, (2014/07/22)
The invention provides compositions and ...
461-97-2 Process route
-
-
(3,5-Dimethylphenyl)(4'-methoxyphenyl)iodonium triflate
-
-
696-62-8
para-iodoanisole
-
-
461-97-2
3,5-dimethylfluorobenzene
-
-
22445-41-6
3,5-dimethylphenyl iodide
-
-
108-38-3,104809-90-7
m-xylene
| Conditions | Yield |
|---|---|
|
With
cesium fluoride;
In
acetonitrile;
at 85 ℃;
for 0.666667h;
GC-MS estimated relative yields;
|
-
-
108-69-0
3,5-dimethylaminoaniline
-
-
461-97-2
3,5-dimethylfluorobenzene
| Conditions | Yield |
|---|---|
|
3,5-dimethylaminoaniline;
With
hydrogen fluoride;
at -30 - 0.5 ℃;
Flow reactor;
Large scale;
With
nitrosylsulfuric acid;
at -3 - 0.5 ℃;
Flow reactor;
Large scale;
|
97.3% |
|
3,5-dimethylaminoaniline;
With
hydrogenchloride; fluoroboric acid; sodium nitrite;
In
water;
at 25 ℃;
for 0.00277778h;
In
chlorobenzene;
at 110 ℃;
for 0.0166667h;
|
88% |
|
3,5-dimethylaminoaniline;
With
hydrogen fluoride;
at 0 - 10 ℃;
for 3h;
Inert atmosphere;
With
sodium nitrite;
at -5 - 60 ℃;
for 11h;
Temperature;
Reagent/catalyst;
|
81% |
|
3,5-dimethylaminoaniline;
With
hydrogenchloride; sodium nitrite;
In
water;
at 0 ℃;
With
tetrafluoroboric acid;
In
water;
at 0 ℃;
for 2h;
at 75 ℃;
|
55% |
|
With
hydrogenchloride; sodium tetrafluoroborate; sodium nitrite;
at 0 - 5 ℃;
|
41% |
|
With
boron trifluoride;
Heating;
|
|
|
Multi-step reaction with 2 steps
1: 48percent tetrafluoroboric acid, sodium nitrite / methanol; H2O
2: Heating
With
tetrafluoroboric acid; sodium nitrite;
In
methanol; water;
|
|
|
With
tetrafluoroboric acid; sodium nitrite;
at -5 - 100 ℃;
for 1.08333h;
Temperature;
|
461-97-2 Upstream products
-
452-64-2
3,4-dimethyl-fluorobenzene
-
108-69-0
3,5-dimethylaminoaniline
-
172975-69-8
3,5-dimethylphenyl boronic acid
-
22445-41-6
3,5-dimethylphenyl iodide
461-97-2 Downstream products
-
315-12-8
2,6-dimethyl-4-fluoro-1-nitro-benzene
-
315-13-9
1-fluoro-3,5-dimethyl-2-nitrobenzene
-
3995-39-9
N,N-diethyl-3,5-dimethylaniline
-
14659-58-6
2‐bromo‐5‐fluoro‐1,3‐dimethylbenzene
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5-Bromo-2-fluoro-m-xyleneCAS：99725-44-7
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-
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