13029-09-9
- Product Name：2,2'-Dibromobiphenyl
- Molecular Formula：C12H8Br2
- Purity：99%
- Molecular Weight：312.004
Product Details;
CasNo： 13029-09-9
Molecular Formula： C12H8Br2
Appearance： white crystalline powder
factory and supplier 13029-09-9 2,2'-Dibromobiphenyl in stock
- Molecular Formula:C12H8Br2
- Molecular Weight:312.004
- Appearance/Colour:white crystalline powder
- Vapor Pressure:0.007-0.27Pa at 20-50℃
- Melting Point:79-83 °C
- Boiling Point:332.884 °C at 760 mmHg
- Flash Point:180.005 °C
- PSA：0.00000
- Density:1.668 g/cm3
- LogP:4.87860
13029-09-9 Relevant articles
A silicon-heteroaromatic system as photosensitizer for light-driven hydrogen production by hydrogenase mimics
Goy, Roman,Apfel, Ulf-Peter,Elleouet, Catherine,Escudero, Daniel,Elstner, Martin,Goerls, Helmar,Talarmin, Jean,Schollhammer, Philippe,Gonzalez, Leticia,Weigand, Wolfgang
, p. 4466 - 4472 (2013)
The utilization of light and inexpensive...
9-Silafluorene and 9-germafluorene: Novel platforms for highly efficient red phosphorescent organic light-emitting diodes
Liu, Xiang-Yang,Tian, Qi-Sheng,Zhao, Danli,Ran, Quan,Liao, Liang-Sheng,Fan, Jian
, p. 8144 - 8151 (2018)
Two novel heterofluorene motifs consisti...
Transition-Metal-Free Approach for the Direct Arylation of Thiophene: Experimental and Theoretical Investigations towards the (Het)-Aryne Route
Demangeat, Catherine,Saied, Tarak,Ramozzi, Romain,Ingrosso, Francesca,Ruiz-Lopez, Manuel,Panossian, Armen,Leroux, Frédéric R.,Fort, Yves,Comoy, Corinne
, p. 547 - 556 (2019)
This paper presents the results of our i...
On-surface synthesis of planar acenesviaregioselective aryl-aryl coupling
Feng, Lin,Wang, Tao,Jia, Hongxing,Huang, Jianmin,Han, Dong,Zhang, Wenzhao,Ding, Honghe,Xu, Qian,Du, Pingwu,Zhu, Junfa
, p. 4890 - 4893 (2020)
The reaction of 2,2'-dibromo-biphenyl on...
REGIOSELECTIVE DIMETALLIERUNG VON AROMATEN. BEQUEMER ZUGANG ZU 2,2'-DISUBSTITUIERTEN BIPHENYLDERIVATEN
Neugebauer, Wolfgang,Kos, Alexander J.,Schleyer, Rague
, p. 107 - 118 (1982)
Lithiation of biphenyl with 2.4 mol of n...
-
Gilman,Gaj
, p. 447,449 (1957)
-
Direct Observation of Aggregation-Induced Emission Mechanism
Corminboeuf, Clémence,Guan, Jianxin,Han, Han,Lin, Kun-Han,Liu, Jitian,Peng, Jie,Prlj, Antonio,Wei, Rong,Yu, Zhihao,Zhao, Dahui,Zheng, Junrong
, p. 14903 - 14909 (2020)
The mechanism of aggregation-induced emi...
Efficient construction of biaryls and macrocyclic cyclophanes via electron-transfer oxidation of Lipshutz cuprates
Miyake, Yoshihiro,Wu, Mo,Rahman, M. Jalilur,Kuwatani, Yoshiyuki,Iyoda, Masahiko
, p. 6110 - 6117 (2006)
An efficient method for the homocoupling...
Pd(OAc)2/PPh3-catalyzed desulfonylative homocoupling of arylsulfonyl chlorides
Zhao, Qiao,Chen, Liangshun,Lang, Hongyue,Wu, Shengying,Wang, Limin
, p. 535 - 538 (2015)
The Pd-catalyzed homodimerization with r...
BN-phenanthryne: Cyclotetramerization of an 1,2-azaborine derivative
Mueller, Matthias,Bettinger, Holger F.,Maichle-Moessmer, Caecilia
, p. 9380 - 9383,4 (2014)
Thermolysis of 9-azido-9-borafluorene in...
ortho-Phenylene-Based Macrocyclic Hydrocarbons Assembled Using Olefin Metathesis
Hartley, C. Scott,Kirinda, Viraj C.,Schrage, Briana R.,Ziegler, Christopher J.
, (2020)
While many foldamer systems reliably fol...
Connecting two phenazines with a four-membered ring: The synthesis, properties and applications of cyclobuta[1,2-: B:3,4- b ′]diphenazines
Yang, Shuaijun,Chu, Ming,Miao, Qian
, p. 3651 - 3657 (2018)
Herein we report cyclobuta[1,2-b:3,4-b′]...
Silicon-Heteroaromatic [FeFe] Hydrogenase Model Complexes: Insight into Protonation, Electrochemical Properties, and Molecular Structures
Goy, Roman,Bertini, Luca,G?rls, Helmar,De Gioia, Luca,Talarmin, Jean,Zampella, Giuseppe,Schollhammer, Philippe,Weigand, Wolfgang
, p. 5061 - 5073 (2015)
To learn from Nature how to create an ef...
"benchtop" Biaryl Coupling Using Pd/Cu Cocatalysis: Application to the Synthesis of Conjugated Polymers
Minus, Matthew B.,Moor, Sarah R.,Pary, Fathima F.,Nirmani,Chwatko, Malgorzata,Okeke, Brandon,Singleton, Josh E.,Nelson, Toby L.,Lynd, Nathaniel A.,Anslyn, Eric V.
supporting information, p. 2873 - 2877 (2021/05/05)
Typically, Suzuki couplings used in poly...
Convenient One-Pot Synthesis of 9 H -Carbazoles by Microwave Irradiation Employing a Green Palladium-Based Nanocatalyst
Steingruber, H. Sebastián,Mendioroz, Pamela,Volpe, María A.,Gerbino, Darío C.
, p. 4048 - 4058 (2021/08/03)
An efficient palladium-catalyzed tandem ...
13029-09-9 Process route
-
-
108-86-1,52753-63-6
bromobenzene
-
-
108-95-2,27073-41-2
phenol
-
-
16400-51-4
3,3'-dibromobiphenyl
-
-
92-86-4
4-(4-bromophenyl)bromobenzene
-
-
13029-09-9
2,2'-dibromobiphenyl
-
-
49602-90-6
2,3′-dibromo-1,1′-biphenyl
-
-
49602-91-7
2-bromo-4'-bromobiphenyl
-
-
57186-90-0
3,4’-dibromobiphenyl
| Conditions | Yield |
|---|---|
|
With
tert.-butylhydroperoxide; iodine;
at 289.9 ℃;
for 0.0272222h;
Product distribution;
|
12.5% 30.9% 16% 17% 19.3% 4.3% |
-
-
108-86-1,52753-63-6
bromobenzene
-
-
583-53-9
2,3-dibromobenzene
-
-
2052-07-5
2-Bromobiphenyl
-
-
13029-09-9
2,2'-dibromobiphenyl
| Conditions | Yield |
|---|---|
|
bromobenzene;
With
tert.-butyl lithium;
In
tetrahydrofuran;
at -80 ℃;
for 1h;
Inert atmosphere;
2,3-dibromobenzene;
In
tetrahydrofuran;
at -50 ℃;
for 2h;
Inert atmosphere;
|
44% 9% |
13029-09-9 Upstream products
-
92-52-4
biphenyl
-
1454-80-4
1,1'-biphenyl-2,2'-diamine
-
54147-91-0
2’-bromo-[1,1’-biphenyl]-2-amine
-
583-53-9
2,3-dibromobenzene
13029-09-9 Downstream products
-
92-52-4
biphenyl
-
2052-07-5
2-Bromobiphenyl
-
18866-42-7
(2'-bromo-biphenyl-2-yl)-triphenyl-silane
-
259-79-0
bisbenzocyclobutene
Relevant Products
-
5-Bromo-2-fluoro-m-xyleneCAS：99725-44-7
-
Tetrabutylphosphonium bromideCAS：3115-68-2
-
1-Decyl-3-Methylimidazolium HexafluorophosphateCAS：362043-46-7
