609-73-4
- Product Name：1-Iodo-2-nitrobenzene
- Molecular Formula：C6H4INO2
- Purity：99%
- Molecular Weight：249.008
Product Details;
CasNo： 609-73-4
Molecular Formula： C6H4INO2
Appearance： solid
factory and supplier 609-73-4 1-Iodo-2-nitrobenzene in stock
- Molecular Formula:C6H4INO2
- Molecular Weight:249.008
- Appearance/Colour:solid
- Vapor Pressure:0.00404mmHg at 25°C
- Melting Point:49-51 °C(lit.)
- Refractive Index:1.663
- Boiling Point:288.5 °C at 760 mmHg
- Flash Point:122.9 °C
- PSA：45.82000
- Density:2.018 g/cm3
- LogP:2.72260
1-Iodo-2-nitrobenzene(Cas 609-73-4) Usage
InChI:InChI=1/C6H4INO2/c7-5-3-1-2-4-6(5)8(9)10/h1-4H
609-73-4 Relevant articles
Nitration of Phenylboron Dichloride with Nitronium Tetrafluoroborate. Attempted Nitration of Iodobenzene and Phenylphosphorous Dichloride
Olah, George A.,Piteau, Mark,Laali, Khosrow,Rao, Chandra B.,Farooq, Omar
, p. 46 - 48 (1990)
Electrophilic nitration of phenylboron d...
Low-temperature and highly efficient liquid-phase catalytic nitration of chlorobenzene with NO2: Remarkably improving the para-selectivity in O2-Ac2O-Hβ composite system
Deng, Renjie,Liu, Pingle,Luo, He'an,Ni, Wenjin,You, Kuiyi,Zhao, Fangfang
, (2020/02/26)
In this work, we developed a low-tempera...
NITRATION
-
Page/Page column 36; 41; 46; 64; 37; 43; 48; 69, (2020/05/28)
The present invention relates to a proce...
Dehydroxyalkylative halogenation of C(aryl)-C bonds of aryl alcohols
Liu, Mingyang,Zhang, Zhanrong,Liu, Huizhen,Wu, Tianbin,Han, Buxing
supporting information, p. 7120 - 7123 (2020/07/14)
We herein report Cu mediated side-direct...
Arene diazonium saccharin intermediates: A greener and cost-effective alternative method for the preparation of aryl iodide
Ghaffari Khaligh, Nader,Rafie Johan, Mohd,Shahnavaz, Zohreh,Zaharani, Lia
, p. 535 - 542 (2020/06/01)
In the current protocol, the arene diazo...
609-73-4 Process route
-
-
591-50-4
iodobenzene
-
-
636-98-6
p-nitrobenzene iodide
-
-
645-00-1
m-iodonitrobenzene
-
-
609-73-4
o-nitroiodobenzene
| Conditions | Yield |
|---|---|
|
With
silver nitrate;
boron trifluoride;
In
acetonitrile;
at 25 ℃;
for 10h;
Product distribution;
competitive nitration benzene, relative rate;
|
17 % Chromat. 3 % Chromat. 80 % Chromat. |
|
With
nitro acetate;
H-ZSM-11;
In
hexane;
at 30 ℃;
Product distribution;
different catalysts;
|
|
|
With
Hβ zeolite; oxygen; dinitrogen tetraoxide;
In
1,2-dichloro-ethane;
at 0 ℃;
for 48h;
Title compound not separated from byproducts.;
|
|
|
With
nitric acid; acetic anhydride;
In
tetrachloromethane;
|
|
|
With
nitrogen dioxide; oxygen; acetic anhydride;
at 35 ℃;
under 3750.38 Torr;
Autoclave;
|
-
-
591-50-4
iodobenzene
-
-
636-98-6
p-nitrobenzene iodide
-
-
609-73-4
o-nitroiodobenzene
| Conditions | Yield |
|---|---|
|
With
nitric acid;
at 50 ℃;
for 3h;
|
29.2% 70.2% |
|
With
trinitratooxovanadium(V);
In
dichloromethane;
for 0.333333h;
Ambient temperature;
|
34% 63% |
|
With
trinitratooxovanadium(V);
In
dichloromethane;
for 0.333333h;
Ambient temperature;
|
62% 35% |
|
With
iodine; silver nitrate; chloro-diphenylphosphine;
In
dichloromethane;
at 20 ℃;
for 24h;
|
10% 57% |
|
With
nitric acid;
|
|
|
With
tetrachloromethane; dinitrogen tetraoxide;
at 20 ℃;
|
|
|
With
tetrachloromethane; aluminium trichloride; dinitrogen tetraoxide;
at 0 - 5 ℃;
|
|
|
With
dinitrogen tetraoxide;
In
acetonitrile;
at 25 ℃;
Product distribution;
Kinetics;
electrochemical nitration (1.6 V), anode: Pt, cathode: Ni; electrolyte: Et4NBF4; other solvents (MeNO2, CH2Cl2); polarization curves;
|
|
|
With
nitric acid;
bleibt beim Umkrystallisieren des Reaktionsprodukts aus Alkohol in der Mutterlauge;
|
|
|
With
nitric acid;
at 0 ℃;
|
|
|
With
nitric acid;
at -30 ℃;
|
|
|
With
nitric acid;
zeolite beta-I;
In
1,2-dichloro-ethane;
|
|
|
With
perchloric acid; montmorillonite K10 supported ammonium nitrate;
at 65 ℃;
for 1.5h;
Title compound not separated from byproducts;
|
|
|
With
phosphorus pentoxide; nitric acid;
In
1,2-dichloro-ethane;
at 40 ℃;
for 4h;
regioselective reaction;
|
|
|
With
lanthanum bis[(trifluoromethyl)sulfonyl]imide; nitric acid;
In
water;
at 85 ℃;
for 24h;
regioselective reaction;
Ionic liquid;
|
|
|
With
nitric acid; acetic anhydride;
In
tetrachloromethane;
at 50 ℃;
for 2h;
regioselective reaction;
|
609-73-4 Upstream products
-
591-50-4
iodobenzene
-
75-52-5
nitromethane
-
591-09-3
nitro acetate
-
827-28-1
2-nitro(dichloroiodo)benzene
609-73-4 Downstream products
-
5320-98-9
N-(2-nitrophenyl)morpholine
-
69180-46-7
2-nitroiodobenzene diacetate
-
16825-77-7
2-nitro-1-iodylbenzene
-
91732-91-1
2'-nitro-10-phenylphenothiazine
Relevant Products
-
3-Iodo-N-phenylcarbazoleCAS：502161-03-7
-
4,10-Dioxatricyclo[5.2.1.02.6]dec-8-ene-3,5-dioneCAS：5426-09-5
-
TriButylMethylAmmonium bis(trifluoromethylsulfonyl)imide
CAS：405514-94-5
