3238-40-2
- Product Name：2,5-Furandicarboxylic acid
- Molecular Formula：C6H4O5
- Purity：99%
- Molecular Weight：156.095
Product Details;
CasNo： 3238-40-2
Molecular Formula： C6H4O5
Appearance： White powder
factory and supplier 3238-40-2 2,5-Furandicarboxylic acid in stock
- Molecular Formula:C6H4O5
- Molecular Weight:156.095
- Appearance/Colour:White powder
- Vapor Pressure:8.9E-08mmHg at 25°C
- Melting Point:>310°C (dec.)
- Refractive Index:1.58
- Boiling Point:419.2 °C at 760 mmHg
- PKA:2.28±0.10(Predicted)
- Flash Point:207.3 °C
- PSA：87.74000
- Density:1.604 g/cm3
- LogP:0.67600
2,5-Furandicarboxylic acid(Cas 3238-40-2) Usage
|
Preparation |
2,5-Furandicarboxylic acid (FDCA) can be produced from biomass or its derived sugars or platform chemicals, and has demonstrated to be a very promising substitute for petroleum-derived polymer products.Chapter 5 - Advances in the synthesis and application of 2,5-furandicarboxylic acid |
|
Synthesis Reference(s) |
Tetrahedron Letters, 26, p. 1777, 1985 DOI: 10.1016/S0040-4039(00)98336-9 |
|
Flammability and Explosibility |
Notclassified |
|
Solubility in organics |
2,5-Furandicarboxylic acid (FDCA) serves as a monomer in various polyesters and is often obtained through the oxidation of 5-hydroxymethylfurfural. In pure solvents and binary mixtures, the solubility of FDCA increased with the increasing temperature. The order from largest to smallest solubility in pure solvents was as follows: methanol, 1-butanol, isobutanol, acetic acid, water, MIBK, ethyl acetate, and acetonitrile.https://doi.org/10.1021/acs.jced.7b00927 |
|
Definition |
ChEBI: A member of the class of furans carrying two carboxy substituents at positions 2 and 5. |
|
Application |
2,5-Furandicarboxylic acid (FDCA) is a renewable, greener substitute for terephthalate in the production of polyesters. It is widely used as a precursor for the synthesis of bio-based polyesters and various other polymers.Applications of FDCA in the synthesis of several metal-organic frameworks (MOFs) have also been reported. |
InChI:InChI=1/C6H4O5/c7-5(8)3-1-2-4(11-3)6(9)10/h1-2H,(H,7,8)(H,9,10)
3238-40-2 Relevant articles
Tunable mixed oxides based on CeO2 for the selective aerobic oxidation of 5-(hydroxymethyl)furfural to FDCA in water
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Chemicals derived from 5-HMF, via select...
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A method to synthesize bimetallic alloys...
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Surface modification of nanomaterials is...
Aerobic oxidation of 5-hydroxymethylfurfural (HMF) effectively catalyzed by a Ce0.8Bi0.2O2-δ supported Pt catalyst at room temperature
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The oxidation of 5-hydroxymethylfurfural...
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The utilization of 5-(hydroxymethyl)furf...
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, p. 2120 - 2124 (2014)
5-hydroxymethylfurfural (HMF) is one of ...
Hydrophilic mesoporous poly(ionic liquid)-supported Au-Pd alloy nanoparticles towards aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid under mild conditions
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, p. 3820 - 3830 (2017)
Design of stable high-performance hetero...
One-pot FDCA diester synthesis from mucic acid and their solvent-free regioselective polytransesterification for production of glycerol-based furanic polyesters
Zhao, Deyang,Delbecq, Frederic,Len, Christophe
, (2019)
A one pot-two step procedure for the syn...
The direct conversion of sugars into 2,5-furandicarboxylic acid in a triphasic system
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, p. 1151 - 1155 (2015)
A one-pot conversion of sugars into 2,5-...
Pt nanoparticles loaded on reduced graphene oxide as an effective catalyst for the direct oxidation of 5-hydroxymethylfurfural (HMF) to produce 2,5-furandicarboxylic acid (FDCA) under mild conditions
Niu, Wenqi,Wang, Ding,Yang, Guohui,Sun, Jian,Wu, Mingbo,Yoneyama, Yoshiharu,Tsubaki, Noritatsu
, p. 1124 - 1129 (2014)
Reduced graphene oxide (RGO) is one of t...
Encapsulation of ultrafine metal-oxide nanoparticles within mesopores for biomass-derived catalytic applications
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, p. 1854 - 1859 (2018)
The development of efficient encapsulati...
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The use of water as an oxygen and hydrog...
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A new 100 % bio-based thermosetting coat...
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, p. 150 - 157 (2018)
The synthesis of furan-2,5-dicarboxylic ...
Nanoscale center-hollowed hexagon MnCo2O4 spinel catalyzed aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
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, p. 19 - 22 (2018)
A series of bimetallic Mn-Co-O catalysts...
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, p. 204 - 209 (2018)
2,5-Furandicarboxylic acid (FDCA) is reg...
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New unsaturated derivatives of the furan...
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, p. 11241 - 11249 (2019)
A novel and enhanced electrosynthesis pr...
MnCo2O4 spinel supported ruthenium catalyst for air-oxidation of HMF to FDCA under aqueous phase and base-free conditions
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, p. 1619 - 1623 (2017)
A new class of MnCo2O4 spinel supported ...
Gold nanoclusters confined in a supercage of Y zeolite for aerobic oxidation of HMF under mild conditions
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, p. 14215 - 14223 (2013)
Au nanoclusters with an average size of ...
A novel magnetic palladium catalyst for the mild aerobic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid in water
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, p. 3194 - 3202 (2015)
In this study, magnetically separable, g...
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, p. 120 - 126 (2012)
5-Hydroxymethyl-2-furfural (HMF) oxidati...
N-doped carbon supported Pt catalyst for base-free oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
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A new kind of N-doped carbon supported P...
An active, selective, and stable manganese oxide-supported atomic Pd catalyst for aerobic oxidation of 5-hydroxymethylfurfural
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Here we report for the first time a Pd-M...
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Hydrogen binding of molecules on solid s...
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The organic ionic oxidant 4-acetamido-2,...
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The catalytic promiscuity of hemoglobin ...
Pd-modified Au on carbon as an effective and durable catalyst for the direct oxidation of HMF to 2,5-furandicarboxylic acid
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, p. 609 - 612 (2013)
Mixed noblility: We show that the modifi...
Selective Aerobic Oxidation of 5-(Hydroxymethyl)furfural over Heterogeneous Silver-Gold Nanoparticle Catalysts
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, p. 5681 - 5696 (2020)
Bimetallic silver-gold alloy nanoparticl...
Supported gold- and silver-based catalysts for the selective aerobic oxidation of 5-(hydroxymethyl)furfural to 2,5-furandicarboxylic acid and 5-hydroxymethyl-2-furancarboxylic acid
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, p. 3530 - 3541 (2018)
The sustainable synthesis of two importa...
Aerobic oxidation of 5-[(formyloxy)methyl]furfural to 2,5-furandicarboxylic acid over MoCuOx catalyst
Wang, Qian,Zhang, Jie,Jia, Wenlong,Yu, Xin,Chen, Jiahong,Sun, Yong,Wei, Zuojun,Yang, Shuliang,Tang, Xing,Zeng, Xianhai,Lin, Lu
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Generally, 5-hydroxymethylfurfural (HMF)...
Efficient synthesis of 2,5-furandicarboxylic acid from biomass-derived 5-hydroxymethylfurfural in 1,4-dioxane/H2O mixture
Fang, Huayu,Ke, Xixian,Li, Tianyuan,Lin, Lu,Liu, Huai,Sun, Yong,Tang, Xing,Xie, Weizhen,Zeng, Xianhai
, (2021/12/17)
The catalytic conversion of 5-hydroxymet...
Efficient Electrocatalytic Oxidation of 5-Hydroxymethylfurfural Coupled with 4-Nitrophenol Hydrogenation in a Water System
Pang, Xuliang,Bai, Hongye,Zhao, Huaiquan,Fan, Weiqiang,Shi, Weidong
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Electrocatalytic conversion of biomass-d...
Enabling Efficient Aerobic 5-Hydroxymethylfurfural Oxidation to 2,5-Furandicarboxylic Acid in Water by Interfacial Engineering Reinforced Cu?Mn Oxides Hollow Nanofiber
Dong, Xuexue,Guo, Zengjing,Song, Hua,Wang, Qian,Wang, Xuyu,Yang, Fu,Yuan, Aihua,Zhang, Yue
, (2022/02/25)
Herein, a one-dimensional hollow nanofib...
3238-40-2 Process route
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7726-95-6
bromine
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2043-98-3
cis-2H,5H-dihydrofuran-2,5-dicarboxylic acid
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3238-40-2
furan-2,5-dicarboxylic acid
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10035-10-6,12258-64-9
hydrogen bromide
| Conditions | Yield |
|---|---|
|
at 140 ℃;
im geschlossenen Rohr;
|
-
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20842-02-8
potassium furan-2-carboxylate
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-
3238-40-2
furan-2,5-dicarboxylic acid
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-
4282-28-4
2,4-furan dicarboxylic acid
| Conditions | Yield |
|---|---|
|
With
cadmium(II) iodide;
at 265 ℃;
for 4h;
Reagent/catalyst;
Temperature;
Overall yield = 89 %;
Inert atmosphere;
Dean-Stark;
Cooling with acetone-dry ice;
|
60.9% |
3238-40-2 Upstream products
-
110-00-9
furan
-
111-65-9
octane
-
1822-71-5
n-pentylsodium
-
67-47-0
5-hydroxymethyl-2-furfuraldehyde
3238-40-2 Downstream products
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4282-32-0
furan-2,5-dicarboxylic acid dimethyl ester
-
10375-34-5
2,5-furandicarbonyl dichloride
-
88-14-2
2-furanoic acid
-
15719-64-9
methylammonium carbonate
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