50446-44-1
- Product Name：1,3,5-Tri(4-carboxyphenyl)benzene
- Molecular Formula：C27H18O6
- Purity：99%
- Molecular Weight：438.436
Product Details;
CasNo： 50446-44-1
Molecular Formula： C27H18O6
factory and supplier 50446-44-1 1,3,5-Tri(4-carboxyphenyl)benzene in stock
- Molecular Formula:C27H18O6
- Molecular Weight:438.436
- Vapor Pressure:0mmHg at 25°C
- Melting Point:322-327 °C
- Refractive Index:1.671
- Boiling Point:710.973°C at 760 mmHg
- PKA:3.46±0.10(Predicted)
- Flash Point:397.736°C
- PSA：111.90000
- Density:1.358g/cm3
- LogP:5.78220
1,3,5-Tri(4-carboxyphenyl)benzene(Cas 50446-44-1) Usage
|
General Description |
1,3,5-Tris(4-carboxyphenyl)benzene (H3BTB) is a star-shaped two-dimensional molecule that forms a self-assembled monolayer (SAM) on a variety of substrates. It can be used as a tritopic bridging ligand that facilitates the functionalization of polyoxometalate-based metal organic frameworks (MOFs) for potential usage in gas storage, gas separation, and catalysis. |
InChI:InChI=1/C27H18O6/c28-25(29)19-7-1-16(2-8-19)22-13-23(17-3-9-20(10-4-17)26(30)31)15-24(14-22)18-5-11-21(12-6-18)27(32)33/h1-15H,(H,28,29)(H,30,31)(H,32,33)
50446-44-1 Relevant articles
Selective Implantation of Diamines for Cooperative Catalysis in Isoreticular Heterometallic Titanium–Organic Frameworks
López-Maya, Elena,Padial, Natalia M.,Castells-Gil, Javier,Ganivet, Carolina R.,Rubio-Gaspar, Ana,Cirujano, Francisco G.,Almora-Barrios, Neyvis,Tatay, Sergio,Navalón, Sergio,Martí-Gastaldo, Carlos
, p. 11868 - 11873 (2021)
We introduce the first example of isoret...
The epoxidation of olefins catalyzed by a new heterogeneous polyoxometalate-based catalyst with hydrogen peroxide
Zhang, Zhenxin,Zhao, Wei,Ma, Baochun,Ding, Yong
, p. 318 - 322 (2010)
Inorganic-organic hybrid material was fo...
Independent verification of the saturation hydrogen uptake in MOF-177 and establishment of a benchmark for hydrogen adsorption in metal-organic frameworks
Furukawa, Hiroyasu,Miller, Michael A.,Yaghi, Omar M.
, p. 3197 - 3204 (2007)
Hydrogen isotherms for MOF-177, Zn4O(1,3...
Removal of toxic dyes from aqueous medium using adenine based bicomponent hydrogel
Sukul, Pradip K.,Malik, Sudip
, p. 1902 - 1915 (2013)
By utilizing hydrogen bonding and π-π st...
Structures and H2 adsorption properties of porous scandium metal-organic frameworks
Ibarra, Ilich A.,Lin, Xiang,Yang, Sihai,Blake, Alexander J.,Walker, Gavin S.,Barnett, Sarah A.,Allan, David R.,Champness, Neil R.,Hubberstey, Peter,Schroeder, Martin
, p. 13671 - 13679 (2010)
Two new three-dimensional ScIII metal-or...
Synthesis of 3,5-Disubstituted Isoxazoles through a 1,3-Dipolar Cycloaddition Reaction between Alkynes and Nitrile Oxides Generated from O-Silylated Hydroxamic Acids
Carloni, Laure-Elie,Mohnani, Stefan,Bonifazi, Davide
supporting information, p. 7322 - 7334 (2019/11/05)
In this paper, we report the regioselect...
A metal oxide catalytic oxidation three 1, 3, 5 - (4 - carboxyl phenyl) benzene method (by machine translation)
-
Paragraph 0028; 0030; 0031; 0032, (2018/07/30)
The invention discloses a metal oxide ca...
Method for preparing polyphenyl polyacid monomers
-
Paragraph 0071-0093, (2018/03/24)
The invention relates to a preparation m...
50446-44-1 Process route
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50446-43-0
1,3,5-tris(4-methyl-phenyl)-benzene
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-
50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene
| Conditions | Yield |
|---|---|
|
With
pyridine; ammonium cerium (IV) nitrate; dihydrogen peroxide; sodium carbonate; cobalt(II) nitrate;
at 110 ℃;
for 6h;
under 15001.5 Torr;
Reagent/catalyst;
Temperature;
Pressure;
Green chemistry;
|
97% |
|
With
2-aminoisonicotinic acid; oxygen; antimony(III) acetate; acetic anhydride; acetic acid; potassium nitrate; 1-aza-adamantane-1-oxide; Dimethyl succinate;
In
1,2-dichloro-benzene;
at 180 ℃;
for 12h;
under 7500.75 Torr;
Reagent/catalyst;
Solvent;
Temperature;
Pressure;
|
92% |
|
With
dihydrogen peroxide; sodium carbonate;
at 100 ℃;
for 12h;
under 7500.75 Torr;
Reagent/catalyst;
Solvent;
|
90% |
|
With
nitric acid;
at 160 - 180 ℃;
im geschlossenen Rohr;
|
|
|
With
nitric acid;
at 170 ℃;
|
-
![dimethyl 5'-(4-(methoxycarbonyl)phenyl)-[1,1:3,1''-terphenyl]-4,4''-dicarboxylate](/upload/2026/1/7c3e42aa-6829-4575-87c8-a49704e9a13c.png)
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117100-41-1
dimethyl 5'-(4-(methoxycarbonyl)phenyl)-[1,1:3,1''-terphenyl]-4,4''-dicarboxylate
-
-
50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene
| Conditions | Yield |
|---|---|
|
With
methanol; sodium hydroxide;
In
tetrahydrofuran;
|
92% |
|
With
water; sodium hydroxide;
In
tetrahydrofuran; methanol;
|
92% |
|
With
water; sodium hydroxide;
In
tetrahydrofuran; methanol;
|
92% |
|
With
sodium hydroxide;
In
tetrahydrofuran; methanol;
at 20 ℃;
for 16h;
|
70% |
|
|
|
|
dimethyl 5'-(4-(methoxycarbonyl)phenyl)-[1,1:3,1''-terphenyl]-4,4''-dicarboxylate;
With
water; sodium hydroxide;
In
methanol;
for 8h;
Reflux;
With
hydrogenchloride;
In
water;
|
|
|
dimethyl 5'-(4-(methoxycarbonyl)phenyl)-[1,1:3,1''-terphenyl]-4,4''-dicarboxylate;
With
potassium hydroxide;
In
tetrahydrofuran; methanol;
Reflux;
With
hydrogenchloride;
In
water;
|
|
|
With
water; sodium hydroxide;
In
tetrahydrofuran;
at 50 ℃;
for 24h;
|
50446-44-1 Upstream products
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50446-43-0
1,3,5-tris(4-methyl-phenyl)-benzene
-
117100-41-1
dimethyl 5'-(4-(methoxycarbonyl)phenyl)-[1,1:3,1''-terphenyl]-4,4''-dicarboxylate
-
124-38-9
carbon dioxide
-
7511-49-1
1,3,5-tris(4-bromophenyl)benzene
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